Synergistic effect of multi-metallic and dual-functional groups of a MOF@rGO layer for the catalytic transfer and shuttle inhibition of lithium-sulfur batteries [0.03%]
用于锂硫电池催化转化和穿梭抑制的MOF@rGO层的多金属及双功能位点协同效应
Zheng Liu,Boman Li,Haoyang Xu et al.
Zheng Liu et al.
We propose a novel multi-functional MOF@rGO layer which is assembled with dual-function groups, multi-metallic doping, and a highly conductive graphene substrate for the modification of lithium sulfur battery separators. The MOF@rGO layer s...
Visible-light-driven borylation and phosphorylation of aryl halides by phosphonium ylide organophotoredox catalysis [0.03%]
可见光驱动的磷叶立德有机光氧化还原催化芳基卤化物硼化和磷化反应
Yasunori Toda,Ren Yamaguchi,Sota Fuwa et al.
Yasunori Toda et al.
A phosphonium ylide-based visible-light organophotoredox catalyst has been successfully applied to boronic ester synthesis using aryl halides and bis(pinacolato)diboron. The excited state of the photoredox catalyst is capable of undergoing ...
Bleaching effect of high refractive index xylylic poly(thiourea)s with "de-conjugated" polarizable hydrogen bonds [0.03%]
具有“去共轭”极化氢键的高折射率对二甲苯多硫脲的漂白效应
Seigo Watanabe,Yoshino Tsunekawa,Kenichi Oyaizu
Seigo Watanabe
Poly(p-xylylene thiourea) (pX-PTU) exhibits high visible-light transparency (%T ≧ 99), a high refractive index (nD = 1.71), and a reasonable Abbe number (νD = 26) owing to "de-conjugated" hydrogen bonds, which inhibit orbital interactions...
Thermally stable lanthanide-doped fluoride nanoscintillators for high-temperature X-ray imaging [0.03%]
用于高温X射线成像的热稳定的稀土掺杂氟化物纳米闪烁体
Zezhen Liu,Huirong Zou,Yubin Wang et al.
Zezhen Liu et al.
We demonstrate that lanthanide-doped fluoride nanoscintillators (NSs) exhibit exceptional thermal stability by balancing multiphonon-assisted luminescence quenching with thermally enhanced carrier transport. This remarkable thermal resilien...
A novel organic/inorganic NH2-UiO-66/ZnO heterojunction for enhanced photocatalytic H2O2 production in pure water [0.03%]
一种新型有机/无机NH2-Uio-66/ZnO异质结用于纯水高效产过氧化氢光催化体系
Ke Zhao,Ni Gan,Meng-Ning Cui et al.
Ke Zhao et al.
A highly active heterojunction photocatalyst was prepared though dispersing NU-66 octahedrons on the surface of ZnO nanofibers. Among the synthesized samples, the optimal composite (NU-66/ZnO-5) demonstrated the highest H2O2 generation rate...
Aggregation-induced emission sonosensitizers: molecular engineering and biomedical applications [0.03%]
聚集诱导发光型声敏化剂：分子工程及生物医学应用
Zekun Du,Wenwen Chen,Mingyu Tian et al.
Zekun Du et al.
Sonodynamic therapy (SDT) has emerged as a promising modality for biomedical applications owing to its non-invasive nature, deep tissue penetration and precise spatiotemporal controllability. However, the clinical potential of conventional ...
Size- and shape-selective substrate deuteration catalyzed by a water-soluble synthetic receptor [0.03%]
由水溶性合成受体催化的尺寸和形状选择性底物氘代作用
Anastasia Karavasili,Jose L Moreno Jr,Grant J Stucky et al.
Anastasia Karavasili et al.
Encapsulation of cyclic alkanones in a water-soluble deep cavitand enables the selective deuteration of substrates. The biomimetic host can selectively and catalytically α-deuterate cycloalkanones in aqueous solution under mild conditions....
Curcumin-based-fluorescent staining and microfluidic detection of microplastics in wastewater effluent [0.03%]
基于姜黄素的微塑料荧光染色及水中微塑料芯片检测技术研究
Juviya Mathew,Haider Warraich,Ratul Kumar Das et al.
Juviya Mathew et al.
We present a fast, eco-friendly method for detecting polyethylene microplastics (
Utilizing an elemental sulfur and molecular hydrogen combination: cobalt silicate-catalyzed thiol synthesis from carbonyls [0.03%]
利用元素硫和分子氢的组合：钴硅酸盐催化羰基合成硫醇
Weixin Qi,Ke Xu,Eiji Yamamoto et al.
Weixin Qi et al.
We describe a cobalt silicate-catalyzed thiol synthesis from carbonyl and nitrile compounds using elemental sulfur and hydrogen. The system yields various thiols efficiently, with high catalyst recyclability. Mechanistic studies suggest the...
A ferroelectric field-engineered carboxylated cellulose/BaTiO3 separator for dendrite-free and stable sodium metal batteries [0.03%]
用于无枝晶和稳定钠金属电池的铁电场工程羧基纤维素/ BaTiO3隔膜
Genmiao Guo,Yun Zhang,Wenjie Zhang et al.
Genmiao Guo et al.
The built-in electric field induced by BaTiO3 homogenizes the interfacial charge distribution, which can facilitate the Na+ ion diffusion and effectively suppress sodium dendrite formation at the source. Such a ferroelectric carboxylated ce...