Metallopeptide-based mimics suggest substrate orientation directs sulphur oxidation vs. hydrogen atom abstraction reactions in mononuclear non-haem iron dioxygenases
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Active metallopeptide based mimics of substrate-bound cysteine dioxygenase (CDO) and isopenicillin-N-synthase (IPNS) suggest that differential reactivity between the two metalloenzymes results from the orientation of a chemically active S(3pπ) dominated MO re... ...
