GeII-H/SiIV-H dehydrocoupling and cycloaddition chemistry of a Ni0 bis(hydridogermylene) complex
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We report the high-yielding synthesis of a bis(hydridogermylene) complex of Ni0 (2). In contrast to known hydridotetrylene chemistry, this complex demonstrates a unique GeII-H/SiIV-H dehydrocoupling reaction, resulting in the formation of an η3-[Ge2Si]-Ni com... ...
