Zn-flux-enabled synthesis of orthorhombic kagome YbFe6Ge6: Yb reduction and magnetic behavior [0.03%]
以Zn助熔剂合成正交kagome结构YbFe6Ge6：Yb还原及磁性行为研究
Rahul Meduri,Grant R Wilkinson,Muhammad Z Idrees et al.
Rahul Meduri et al.
Single crystals of an orthorhombic polymorph of kagome metal YbFe6Ge6 were grown from Zn flux. This Zn-flux-stabilized phase exhibits mixed Yb valency and magnetic behavior that differs from its hexagonal counterpart, underscoring the profo...
Solvent-triggered breakdown of solid solution behaviour enables direct enantioselective crystallization of RS-phenprocoumon [0.03%]
溶剂触发的固溶体行为破坏直接拆分苯丙香豆素外消旋体结晶的研究
Yihua Jiang,Sokhna Souare,Koen Robeyns et al.
Yihua Jiang et al.
We show that solvent selection plays a decisive role in chiral resolution of RS-phenprocoumon-quinidine. In particular, formation of a bis-acetone solvate suppresses solid solution formation, and affords spontaneous enantioselective crystal...
Engineered covalent organic framework-based nanosystem for strengthening pyroptosis-mediated tumor immunotherapy [0.03%]
一种工程化共价有机框架纳米系统用于增强肿瘤免疫治疗中的焦亡效应
Yujie Wen,Xuesheng Tan,Cheng Han et al.
Yujie Wen et al.
Pyroptosis-based nanomedicine holds inspiring potential to transform "cold tumors" into "hot tumors" within the tumor immunosuppressive microenvironment, thus significantly advancing the progress of tumor immunotherapy. However, developing ...
A biocatalytic reticular framework via enzyme immobilization for environmental pollutant monitoring [0.03%]
一种通过固定化酶构建的生物催化网络框架用于环境污染物监测
Rui Gao,Xiaoxue Kou,Jing Li et al.
Rui Gao et al.
The growing prevalence of anthropogenic pollutants demands the advancement of environmental monitoring technologies. Biocatalytic sensing, leveraging enzymatic specificity and efficiency, offers a promising alternative, yet the structural f...
Opposite enantioselectivities displayed by supramolecular helical catalysts with non-enantiomeric "sergeants" [0.03%]
非对映体“ Sergeants”的超分子手性催化剂表现出相反的手性选择性
Antoine Perennes,Ádám Müller,Tomoyuki Ikai et al.
Antoine Perennes et al.
Triarylamine trisamide (TATA) coassemblies composed of one achiral phosphine-based monomer and one chiral monomer, as the "soldier" and "sergeant" respectively, were found to adopt opposite handednesses and favour enantiomers of a catalytic...
Copper-catalysed decarboxylative alkynylation-cyclization reaction of propargylic cyclic carbonates with nitrile imines to access tetrasubstituted pyrazoles [0.03%]
铜催化丙烯基环碳酸酯与腈亚胺的脱羧炔基化-环化反应以合成四取代吡唑化合物
Xiaowen Yu,Jinxia Li,Jiongjiong Duan et al.
Xiaowen Yu et al.
Herein, we report a robust copper-catalyzed decarboxylative alkynylation-cyclization cascade that enables the efficient synthesis of diverse tetrasubstituted pyrazoles under mild conditions, addressing the long-standing regioselectivity cha...
From local to global or semilocal aromaticity: singlet-triplet switching in porphyrin tapes [0.03%]
从局部到全局或半局部芳香性：卟啉带单重态-三重态切换
Sergio Moles Quintero,Luis Álvarez-Thon,William Tiznado et al.
Sergio Moles Quintero et al.
Magnetic and electronic analyses of porphyrin tapes uncover a transition from local aromaticity in the ground state to extended/semilocal aromaticity in the triplet state. This reorganization reduces the singlet-triplet gap, establishing po...
Selective etching of binary nanoparticle superlattices via thermally induced asymmetric ligand evolution [0.03%]
基于热效应的不对称配体演化的二元纳米晶超晶格的选择性刻蚀
Di Lei,Hao Wang,Ting Wang et al.
Di Lei et al.
We report a method to selectively etch either component in NaYF4/Fe3O4 binary nanoparticle superlattices using a single etchant. Thermally-induced evolution of oleate ligands on the NaYF4 nanoparticles reverses their relative etching suscep...
Fast-track discovery of MOF-derived M@NC catalysts for HMF-to-FDCA oxidation via DFT prescreening and Box-Behnken optimization [0.03%]
基于DFT预筛和Box-Behnken优化的MOF衍生M@NC催化剂用于HMF氧化制备FDCA的快速发现方法
Zhan Chen,Zhenzhi Xia,Zekun Hu et al.
Zhan Chen et al.
Efficient HMF-to-FDCA oxidation requires the co-optimization of intrinsic active-site chemistry and a multidimensional reaction window. Here we report a fast-track DFT-to-experiment workflow that accelerates both catalyst selection and cond...
Mitochondria-targeted NIR-II organic probes for imaging-guided photodynamic therapy [0.03%]
近红外二区线粒体靶向有机探针用于成像引导的光动力治疗研究
Hui Zhou,Yuquan Ji,Siyang Yu et al.
Hui Zhou et al.
Fluorescence imaging-guided photodynamic therapy (PDT) is a promising modality for precision cancer treatment, yet most organic photosensitizers emitting in the visible or first near-infrared (NIR-I) region suffer from limited penetration, ...