Ligand-driven redox transformations and catalytic activities of mononuclear copper complexes: structural and spectroscopic insights [0.03%]
配体驱动的单核铜配合物中的氧化还原转换和催化活性：结构与光谱研究透视
Soumen Rakshit,Jyotirmoy Mitra,Rajat Saha et al.
Soumen Rakshit et al.
Eight mononuclear complexes have been synthesized, namely: [(L1)CuI]ClO4 (1), [(L2)CuI]ClO4·CH3CN (2·CH3CN), [(L2)CuII(DMF)](ClO4)2·2DMF·H2O (3·2DMF·H2O), [(L1)CuII(MeCN)](ClO4)2 (4), [(L1)CuII(Cl)]PF6 (5), [(tren)CuII(MeCN)](ClO4)2 (...
Adenine/adenine contacts defined in the G-quadruplex for highly selective Tb3+ binding [0.03%]
腺嘌呤/腺嘌呤相互作用在G-四链体中定义了Tb3+的高选择性结合位点
Yulu Ru,Jiahui Chen,Qinxin Li et al.
Yulu Ru et al.
The folding of nucleic acids is strongly dependent on metal ions. For example, G-quadruplex (G4) structures are usually determined by the specific K+/Na+ coordination. However, G4 constructs highly selective to high-valent metal ions (for i...
Significant electrochemical performance improvement of an anion MOF-based solid-state electrolyte across a wide temperature range via an ion exchange strategy [0.03%]
通过离子交换策略在宽温度范围内显著提高阴离子MOF基固态电解质的电化学性能
Changqi Gu,Wenyu Ding,Sheng Jin et al.
Changqi Gu et al.
Low ionic conductivity (σ) and high activation energy (Ea) seriously hinder the development of solid-state electrolytes (SSEs). Herein, a series of post-modified Li+@Ni-MOF-X (X = 1, 2, and 3) materials were synthesized via an ion exchange...
Redefining platinum(IV) chemotherapy: α-tocopherol succinate functionalization and nanoparticle encapsulation to improve cisplatin- and oxaliplatin-based therapies [0.03%]
重新定义铂(IV)化疗：α-生育酚琥珀酸修饰和纳米颗粒包封，以改善顺铂和奥沙利铂的治疗效果
Carlo Marotta,Damiano Cirri,Maria Chiara Maimone et al.
Carlo Marotta et al.
Platinum(IV) prodrugs offer a promising strategy to overcome the limitations of cisplatin and oxaliplatin, including systemic toxicity and acquired resistance. In this study, two novel α-tocopherol succinate-functionalized Pt(IV) complexes...
Luminescent ionic heterobimetallic diphosphine-β-diketiminate complexes [0.03%]
含磷配体和β-二酮亚胺配体的异金属离子型发光配合物
Steven Kebernik,Frederic Krätschmer,Xiaofei Sun et al.
Steven Kebernik et al.
The syntheses of luminescent heterobimetallic ionic complexes based on the bis(phosphine)-functionalized β-diketiminate ligand [HC{(CH3)C}2{(o-[P(C6H5)2]2C6H4)N}2]- (PNac) are reported. This orthogonal ligand is characterized by its PNNP p...
Strategic fluorine atom positioning in carbazolyl oxadiazole derivatives: constructing asymmetric Ir(III) complexes for enhanced electroluminescence performance [0.03%]
咔唑基噁二唑衍生物中氟原子的 strategic 位置对不对称铱配合物高效发光性能的影响
Jia-Wei Liu,Xue-Cheng Wang,Li-Jing Wen et al.
Jia-Wei Liu et al.
Asymmetric coordination Ir(III) complexes hold promise as luminescent materials for organic light-emitting diodes (OLEDs). This study provides an efficient synthetic strategy for the construction of asymmetric complexes through novel carbaz...
Varying anion coordination in new families of dinuclear NiIILnIII complexes: zero-field slow relaxation of magnetization and theoretical validations [0.03%]
新型双核NiIIILnIII配合物家族中阴离子配位的多样性：零场磁化率缓慢弛豫及理论验证
Biswarup Dutta,Ibtesham Tarannum,Zvonko Jagličić et al.
Biswarup Dutta et al.
Herein, we report the room-temperature synthesis, structural characterization, and magnetic performances of two new families of dinuclear NiII-LnIII complexes, [NiLn(HL)2(NO3)3]·nH2O·CH3CN (1a-1c) (n = 1 for Ln = Tb, and n = 1.5 for Dy an...
Ligand modification for the tuning of activity and selectivity in the chemoselective transfer hydrogenation of α,β-unsaturated carbonyls using EtOH as a hydrogen source [0.03%]
以EtOH作为氢源的α,β-不饱和羰基化合物化学选择性转移氢化的活性和选择性的调节——配体的修饰与调控
Alicia Beaufils,Nicole Elia,Sabela Reuge et al.
Alicia Beaufils et al.
The selective reduction of α,β-unsaturated ketones, either at the olefinic or the carbonyl site, offers attractive synthetic opportunities. While carbonyl reduction is well established, selective olefin reduction is less common, particula...
Synthesis, structure and slow magnetic relaxation of lanthanoid coordination polymers based on ethynyl-bridged picolinate ligands [0.03%]
乙炔基并吡啶酸配体的镧系配合物多聚体的合成、结构及磁性质研究
Verónica Jornet-Mollá,Carlos J Gómez-García,Miquel J Dolz-Lozano et al.
Verónica Jornet-Mollá et al.
A heteroditopic ligand (H2L1) containing picolinate and benzoate moieties segmented by a triple bond has been used in the preparation of a family of isostructural coordination polymers of the formula [(CH3)2NH2][Ln((H2O)2L1)2] (Ln = Eu (1),...
Synergistic WO3-PBI hybrid electrochromic materials with an enhanced diffusion coefficient and cycling reversibility inspired by the "Big Rocks" theory [0.03%]
受“大石头”理论启发的WO3-PBI混杂电致变色材料具有增强的扩散系数和循环可逆性
Chunxia Hua,Huanyu Tan,Shujin Ma et al.
Chunxia Hua et al.
The key technology underlying intelligent energy conversion and display systems hinges on high-performance electrochromic materials. To drive their electrochemical redox reactions, facilitating ion/electron transport and intercalation/deint...