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Synthesis, structure and slow magnetic relaxation of lanthanoid coordination polymers based on ethynyl-bridged picolinate ligands

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A heteroditopic ligand (H2L1) containing picolinate and benzoate moieties segmented by a triple bond has been used in the preparation of a family of isostructural coordination polymers of the formula [(CH3)2NH2][Ln((H2O)2L1)2] (Ln = Eu (1), Gd (2), Tb (3), Dy ... ...