Introducing (inter-)halogen polysulfates - a study on the influence of halogen bonding on weakly coordinating anions [0.03%]
介绍（互）卤化物多硫酸盐的研究-卤素键对弱配位阴离子的影响研究
Jan Langwald,Rosa M Gomila,David van Gerven et al.
Jan Langwald et al.
We present the isolation and structural elucidation of the first (inter-)halogen polysulfates [I3]4[S4O13]2(SO3), [IBr2]2[S4O13], [ICl2][HS2O7] and [ICl2]2[S2O7]. All compounds are accessible by the reaction of I2, Br2 and ICl3 with neat SO...
Construction of high-performance single-molecule magnets with a high-axiality coordination environment surrounding a lanthanide spin center based on macrocyclic ligands [0.03%]
基于大环配体的轴向高 lanthanide 单分子磁体的构筑
Han Yan,Wen-Bin Sun
Han Yan
With the advent of the information age, a pressing imperative for larger capacity, higher speeds and miniaturized devices to process and store information is emerging. Single-molecule magnets (SMMs), as molecular nanomagnets with a unique a...
R CuMg2 compounds (R = Dy-Tm, Lu): crystal structure, chemical bonding and magnetic properties [0.03%]
R-CuMg2(R=Dy-Tm，Lu)化合物的晶体结构、化学键和磁性性质研究
P Solokha,D Skachko,R Freccero et al.
P Solokha et al.
The RCuMg2 intermetallics (R = Dy-Tm, Lu) were found to crystallize in a new structure type (DyCuMg2, oP32, space group: Pmma, a = 13.5397(4), b = 3.7594(1), c = 13.7985(4) Å). This unique crystal space is characterized by the presence of ...
Unveiling the interplay: comparing solvent extraction, structure, and stability constants in a phenanthroline diamide system with trivalent lanthanides [0.03%]
层层剖析：三价稀土配合物体系中溶剂萃取、构效关系及稳定常数的比较研究
Emma M Archer,Correy R Vigil,Shane S Galley et al.
Emma M Archer et al.
Phenanthroline diamide ligands have shown promise as extractants for the selective separation of the An(III) from the Ln(III) in used nuclear fuel recycling. To enhance the effectiveness of these ligands, a fundamental understanding of thei...
Crystallographic elucidation of an isophthalic-derived amido Schiff base Cu(II) coordination polymer: a photosensitive Schottky device [0.03%]
基于均苯三甲酸衍生物胺醛缩合配体Cu(II)配位聚合物的晶体学研究及Schottky器件的光电性能
Md Sanaul Islam,Pubali Das,K Mohamed Yusuf Baig et al.
Md Sanaul Islam et al.
Herein, we synthesized an isophthalic-derived two-arm-containing amido Schiff base ligand (H2L), bis(2-hydroxybenzylidene)isophthalohydrazide, and its copper complex (complex 1), characterized by elemental analysis, IR spectra, mass spectro...
A coordinatively unsaturated mononuclear europium(III) complex: a luminescent sensor for adenosine monophosphate in aqueous media [0.03%]
一个配位不饱和的单核铕(Ⅲ)配合物：作为水介质中腺苷酸磷酸的发光探针
Raju Biswas,Manik Das,Toushique Ahmed et al.
Raju Biswas et al.
Luminescent probes for sensing adenosine monophosphate (AMP), particularly in the presence of ADP and ATP, are rare. Herein, we report a novel Eu(III) complex, [(H2O)(L)2Eu(SO3CF3)2](SO3CF3) (EuC), for this purpose, which is synthesized thr...
Perylenediimide-based metal-organic frameworks: structural, electrochemical and spectroelectrochemical characterisation [0.03%]
基于perylenediimide的金属有机框架：结构、电化学和光谱电化学特征研究
Joseph O Ogar,E Stephen Davies,Asia R Y Almuhana et al.
Joseph O Ogar et al.
The electrochemical and spectroelectrochemical behaviour of metal-organic frameworks (MOFs) using a perylene diimide (PDI) based ligand is reported. Through suitable functionalisation, a PDI-based ligand is made soluble, allowing successful...
Biochemical assays for evaluating anticancer activity and validating mechanisms of action in coordination/organometallic compounds: a review [0.03%]
用于评估配位/有机金属化合物抗癌活性和验证作用机制的生化测定法：综述
Dalal Alezi,Abrar S Iskandrani,Ehab M M Ali et al.
Dalal Alezi et al.
Research on metal-based coordination and organometallic compounds is flourishing due to their potential to overcome drug resistance, reduce systemic toxicity, and target diverse cellular pathways. Driven by the success of cisplatin and othe...
Pressure-induced tuning of the triangular-honeycomb structure of ferroelectric quantum spin liquid candidate, TbInO3 [0.03%]
压力调控铁电量子自旋液体候选材料TbInO3中的三角-蜂窝结构
Christopher J Ridley,Aly H Abdeldaim,Craig L Bull et al.
Christopher J Ridley et al.
The pressure response of the triangular-honeycomb-structured quantum spin liquid candidate, TbInO3, has been determined via neutron powder diffraction up to 5.75(5) GPa. The system retains hexagonal symmetry up to the maximum pressure consi...
A digermylene (LGeI-GeIL) on an N-heterocyclic carbene-fluorenyl hybrid ligand (L) and its oxidation by TEMPO and Ph2E2 (E = S, Se) [0.03%]
一种N-杂环卡宾-芴基杂化配体(L)的二茂锗(LGeI-GeIL)及其TEMPO和Ph2E2(E=S, Se)氧化产物的研究
Sumana Mondal,Subham Sarkar,Chhotan Mandal et al.
Sumana Mondal et al.
A hybrid N-heterocyclic carbene (NHC)-fluorenyl ligand (L) supported GeIICl complex ([LGeCl]; 1) has been made from GeCl2(dioxane) and [LK]n. Compound 1 is reduced by Jones' MgI2 dimer [(MesNacnacMg)2] (MesNacnac = [{(Mes)NCMe}2CH]-; Mes = ...