Synthesis of a series of PNC pincer ligand-supported Pt complexes, and an initial exploration of their reactivity [0.03%]
一系列PNC钳形配体支持的Pt配合物的合成及其反应性的初步研究
Mikhail A Losev,Azamat Yessengazin,Robert R Fayzullin et al.
Mikhail A Losev et al.
A Pt-Cl complex supported by a PNC (phosphine, pyridine, and phenyl) donor pincer ligand was synthesized. The complex proved to be remarkably stable under air and ambient conditions. Cationic complexes with coordinated DMSO or CO were obtai...
Synthesis and characterization of π cyclopentadienyl complexes of manganese and iron with one to five fluorosilyl substituents. Crystal and molecular structures of [Mn(C5Br{SiMe2F}4)(CO)3] and [Mn(C5{SiMe2F}5)(CO)3] [0.03%]
含有一到五个氟代硅基取代基的锰和铁π-环戊二烯配合物的合成与表征．[Mn(C5Br(SiMe2F)4)(CO)3]和[Mn(C5(SiMe2F)5)(CO)3]晶体及分子结构
Karlheinz Sünkel,Stephanie Bernhartzeder,Susanna Schubert
Karlheinz Sünkel
The reaction of AgSbF6 with the cymantrenyl hydrosilanes [Mn{C5Br5-n(SiMe2H)n}(CO)3] (n = 1-5) gives the corresponding fluorosilanes. With the ferrocenylhydrosilanes [Fe{C5Br5-n(SiMe2H)n}(C5H5)] fluorination and oxidation to give the ferric...
Defect engineering for enhancing the piezoelectric catalytic activity of Bi2S3 for hydrogen production [0.03%]
缺陷工程增强Bi2S3的压电催化产氢性能研究
Qifeng Jia,Meng Li,Weiji Sun
Qifeng Jia
Piezocatalysis has emerged as a promising strategy for sustainable hydrogen production, yet its efficiency remains limited by insufficient charge separation and sluggish surface reactions. In this study, we demonstrate that introducing sulf...
Design and transformation of ACQphores into AIEgens: toward MOF-based advanced sensing applications [0.03%]
ACQ基元向AIE基元的转变及设计：基于MOFs的高级传感应用研究
Khushboo Rathore,Anita Nehra,Ritambhara Jangir
Khushboo Rathore
Aggregation-induced emission (AIE) has emerged as a groundbreaking optoelectronic phenomenon that overcomes the limitations of aggregation-caused quenching (ACQ), enabling the development of highly light-emitting substances with broad appli...
Prussian blue analogues for high-performance sodium ion battery cathodes: recent advances and challenges [0.03%]
高性能钠离子电池正极普鲁士蓝类化合物的研究进展与挑战
Shumin Sun,Xingqi Jiang,Ziyu Wang et al.
Shumin Sun et al.
Prussian blue analogues (PBAs) have gained considerable attention as promising cathode materials for sodium-ion batteries (SIBs) due to their three-dimensional open framework structure, cost-effectiveness, and high theoretical capacity. Cur...
Comparative investigation and mechanistic analysis of textured PMN-30PT ceramics using BaTiO3 and PbTiO3 templates [0.03%]
基于BaTiO3和PT模板的PMN-30PT铁电陶瓷织构化研究及机理分析
Xi Ouyang,Manwen Yao,Tongqing Yang
Xi Ouyang
Homogeneous PbTiO3 (PT) templates are considered an ideal choice for textured lead-based piezoceramics. In order to further investigate the texture mechanism and topological microcrystal conversion of PT templates, a comparative investigati...
Ultramicroporous Al(III) MOFs with selective CO2 adsorption, acid resistance, and efficient Cr(VI) sorption properties [0.03%]
具有选择性二氧化碳吸附、耐酸性和高效六价铬吸附性能的超微孔铝基金属有机框架材料
Dimitrios A Evangelou,Eleni C Makri,Nikolaos Pliatsios et al.
Dimitrios A Evangelou et al.
In the present work, we report the hydrothermal synthesis and detailed characterization of a series of ultramicroporous, luminescent, multivariate metal-organic frameworks (MOFs) with the general formula [Al(OH)(IATP)1-x(NH2-BDC)x], constru...
A systematic study of naphthyridine-derived ligands for well-defined silver(I) dimers [0.03%]
基于萘啶的配体形成定义明确的银(I)二聚物的系统研究
Sofia Teixeira Bavaresco,Nina P Marquard,Emily Miura-Stempel et al.
Sofia Teixeira Bavaresco et al.
Dinuclear silver(I) complexes have recently gained attention for potential applications in visible light photochemistry. Our group has demonstrated that strong visible light absorption can occur in silver(I) dimers featuring redox-active na...
A mitochondria-targeted iridium complex activates anti-tumour immunity by regulating zinc homeostasis in cancer cells and macrophages [0.03%]
一种靶向线粒体的铱配合物通过调节癌细胞和巨噬细胞中的锌稳态来激活抗肿瘤免疫作用
Jun-Jian Lu,Xi-Song Feng,Yu Liu et al.
Jun-Jian Lu et al.
Intracellular zinc homeostasis and subcellular compartmentalization are exquisitely regulated, playing critical roles in immune regulation, such as inducing inflammatory programmed cell death, producing high levels of interferons and inflam...
Semiconductor-to-semimetal transition on Te doping in a new semiconducting material Ba2.75Pb1.1Sb4.1Se10 [0.03%]
Te掺杂在新型半导体材料Ba2.75Pb1.1Sb4.1Se10中诱导产生半导体到半金属的相变
Swati,Subhendu Jana,Sayani Barman et al.
Swati et al.
Semiconducting antimony-containing chalcogenides are an emerging class of materials for their applications in the thermoelectric and optoelectronic fields. A series of new polycrystalline antimony-containing chalcogenides Ba2.75Pb1.1Sb4.1Se...