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Ligand-driven redox transformations and catalytic activities of mononuclear copper complexes: structural and spectroscopic insights

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Eight mononuclear complexes have been synthesized, namely: [(L1)CuI]ClO4 (1), [(L2)CuI]ClO4·CH3CN (2·CH3CN), [(L2)CuII(DMF)](ClO4)2·2DMF·H2O (3·2DMF·H2O), [(L1)CuII(MeCN)](ClO4)2 (4), [(L1)CuII(Cl)]PF6 (5), [(tren)CuII(MeCN)](ClO4)2 (6), [(tren)CuII(Cl)]... ...