Mechanistic insight into cooperative catalysis with pentanuclear nickel clusters: catalytic alkene dimerization and silyl-silylene and silylyne clusters [0.03%]
五核镍配合物协同催化的机理研究：烯烃二聚化和硅基-硅烯及硅炔金属簇的形成
Junyang Liu,Kethya Sum,Samuel A Johnson
Junyang Liu
This work gives structural insights into potential intermediates relevant to the mechanism of stereoselective catalysis by pentanuclear Ni complexes, such as the previously reported stereoselective dimerization of norbornene to the C2 symme...
Tuning the visible absorption of manganese(I) tris(diisocyanide) complexes [0.03%]
调谐锰(I)三(N,N-二烃基异氰化物)配合物的可见吸收光谱
Anette S Hansen,Petter Persson,Christina Wegeberg
Anette S Hansen
With the aim of using transition metal complexes as photosensitisers, it is important that they feature visible absorption and high photostability. While arylisocyanide ligands have previously been used to improve the metal-to-ligand charge...
Expanding the zinc precursor toolbox: a comparative study of precursors for thermal ALD of ZnO thin films [0.03%]
锌前驱体工具箱的扩展：用于热ALD法生长ZnO薄膜的前驱体的比较研究
Jorit Obenlüneschloß,Rajesh Pathak,Vepa Rozyyev et al.
Jorit Obenlüneschloß et al.
Atomic layer deposition (ALD) of zinc oxide (ZnO) has been widely researched using diethyl zinc (DEZ)-based methods. The significant importance of thin films of ZnO as transparent conductive oxides (TCO) in optoelectronic devices and photov...
Bicarbonate anion coordination assisted CO2 capture by using urea-morpholine hybrid receptors in water [0.03%]
用水作溶剂采用尿素-茂金属杂环受体辅助碳酸根离子配位捕集二氧化碳
Zhiwen Sun,Ji Wang,Qingling Nie et al.
Zhiwen Sun et al.
The development of energy-efficient sorbents for aqueous CO2 capture remains a significant challenge. This work presents a new design strategy by integrating a tertiary amine (morpholine) with a urea motif into a single molecular receptor. ...
Magneto-structural correlations in cobalt(II)-phenanthroline compounds with chloranilic acid [0.03%]
氯苯醌配合物中钴(II)和菲咯啉的磁结构相关性研究
Filip Torić,Lidija Androš Dubraja,Mirta Herak et al.
Filip Torić et al.
The impact of subtle modification of the environment on magnetic properties, by exchanging only solvent molecules, was investigated using a novel series of cobalt(II) compounds as a case study. Three new cobalt(II) complexes with a phenanth...
Post-synthetic citrate modification of Eu(III) doped hydroxyapatite nanoparticles for enhanced cellular uptake in bioimaging applications [0.03%]
用于生物医学成像的Eu(III)掺杂的羟基磷灰石纳米颗粒的抗坏血酸后修饰以增强细胞摄取
Thoudam Chanchan Devi,Pritam Das,Souma Ghosh et al.
Thoudam Chanchan Devi et al.
Interest in the development of various innovative synthesis approaches for producing biomimetic nanoparticles (NPs) arises from their remarkable ability to achieve effective cellular uptake for various biomedical applications. In this study...
Synergistic ternary polypyrrole/WO3/MWCNT nanocomposites for environmental remediation and electrochemical water splitting [0.03%]
用于环境修复和电化学水解的协同三元聚吡咯/钨酸盐/多壁碳纳米管纳米复合材料
Nafees Ahmad,Greesh Kumar,Irfanul Haq Faridi et al.
Nafees Ahmad et al.
The development of cost-effective and multifunctional nanocatalysts is essential to address pressing environmental and energy challenges, particularly organic pollutant removal and sustainable hydrogen production. Herein, we report a ternar...
Cu-exchanged phosphomolybdic acid induced a solvent effect to enhance alkene epoxidation with H2O2 [0.03%]
铜取代磷钼酸诱导溶剂效应增强H2O2氧化烯烃制环氧烷副产物水合物反应路径选择性
Xiaojing Song,Shuang Liu,Jing Wang et al.
Xiaojing Song et al.
Solvent-mediated alkene epoxidation using H2O2 oxidant is significantly enhanced by a Cu-substituted phosphomolybdic acid anchored on triphenylamine-functionalized porous organic polymers (CuPMA/POPs). The immobilization of the CuPMA cluste...
Ba3BiPbREO(BO3)4 (RE = Pr, Nd, Gd, and Dy): two-dimensional rare-earth antiferromagnets with a geometrically-perfect triangular lattice directed by a triangular BO3 unit [0.03%]
Ba3BiPbREEO(BO3)4（RE=Pr，Nd，Gd和Dy）：由三角形BO3基团决定的二维几何理想三角晶格稀土反铁磁体
Yun Lv,Yanhong Wang,Nian Shi et al.
Yun Lv et al.
The synthesis of novel two-dimensional (2D) triangular frustrated compounds is important for providing various platforms to investigate exotic quantum magnetism. Here, we successfully synthesised a series of RE-based magnetic compounds Ba3B...
The roles of Asn7 and Trp67 in tuning the ferryl haem form of Staphylococcus aureus IsdG [0.03%]
Asn7和Trp67在调谐金黄色葡萄球菌IsdG的铁 holm形式中的作用
A Grover,A Nabi,M A Conger et al.
A Grover et al.
IsdG is a member of the Staphylococcus aureus iron-regulated surface determinant system that degrades haem scavanged from a human host to a mixture of staphylobilin and biliverdin; the rate-limiting step of this enzyme is the rearrangment o...