Mechanistic insight into cooperative catalysis with pentanuclear nickel clusters: catalytic alkene dimerization and silyl-silylene and silylyne clusters
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This work gives structural insights into potential intermediates relevant to the mechanism of stereoselective catalysis by pentanuclear Ni complexes, such as the previously reported stereoselective dimerization of norbornene to the C2 symmetric (Z) anti-(bis-2... ...