Modulating Basicity in Mg-Al Oxides for Selective N‑Alkylation of BIT with Improved Catalytic Performance [0.03%]
调控镁铝氧化物碱性的苯并异噻唑的N-烷基化反应及其对催化剂性能的影响
Wenyuan Zhang,Haoyu Yao,Shanshan Liang et al.
Wenyuan Zhang et al.
Heterogeneous catalytic N-alkylation has increasingly been recognized as a sustainable approach for the formation of C-N bonds, particularly in the synthesis of high-value nitrogen compounds. Based on the characteristic that calcined hydrot...
Dynamic Adsorption of Low-Concentration Formaldehyde Using One-Step Synthesized Amino-Functionalized Hyper-Cross-Linked Ionic Copolymers [0.03%]
一步合成氨基功能化高交联离子共聚物吸附低浓度甲醛动态吸附研究
Tian-Tian Jiao,Hui-Ying Fan,Ran-Ran Hou et al.
Tian-Tian Jiao et al.
Formaldehyde (FA) emissions seriously influence the environment and human health, while traditional adsorbents are restricted by low capacity and poor selectivity. To address these limitations, amino-functional hyper-cross-linked copolymer ...
How to Efficiently Design 2D Materials for Electrochemical Applications Using Machine Learning [0.03%]
基于机器学习的二维材料电化学应用高效设计方法研究
Pawin Iamprasertkun
Pawin Iamprasertkun
Two dimensional (2D) materials have transitioned from lab findings to potential applications. Starting with the isolation of graphene, the field has rapidly expanded to encompass a broad spectrum of materials, including transition metal dic...
Sustainable and Highly Efficient Synthesis of Reactive Diluents from Renewable Sources for Property-Enhancing Purposes in Glass-Containing Material Composites [0.03%]
基于可再生资源的改性稀释剂的可持续高效合成用于玻璃增强复合材料性能方面的影响研究
Vojtěch Jašek,Otakar Bartoš,Jan Prokeš et al.
Vojtěch Jašek et al.
Biobased reactive diluents are an alternative to fossil-based compounds, such as styrene, used in industrial-scale manufacturing. We proposed a more scalable, sustainable, and applicable synthesis of methacrylated biobased monomers involvin...
Computational Insight into the Photocatalytic Splitting of H2S during Gas-Solid Phase and Aqueous Phase Reactions [0.03%]
计算揭示气固相和水相反应过程中H2S光催化分解的机理
Yue-Wen Yang,Zhi-Hao Luo,Jia-Sheng Zhou et al.
Yue-Wen Yang et al.
Hydrogen sulfide (H2S) is a hazardous byproduct of industrial processes and poses significant environmental and health risks. Conventional methods for H2S removal are not cost-effective, motivating the exploration of photocatalytic splittin...
Controlled Chain-Walking Polymerization in the Gas Phase to Ultrahigh Molecular Weight Polyethylene [0.03%]
气相可控链行走聚乙烯的超大规模化聚合
Yan Wang,Shuaikang Li,Mengyao Zhang et al.
Yan Wang et al.
This study presents an unconventional approach for the gas-phase synthesis of ultrahigh molecular weight polyethylene (UHMWPE) using sterically hindered 2,6-bis-(diarylmethyl) α-diimine palladium-(II) catalysts. By leveraging a self-suppor...
Asal Ghaffari Zaki,Hamzah Issa,Seyed Mohammad Miri et al.
Asal Ghaffari Zaki et al.
Hydrogen sulfide (H2S) is a signaling molecule with a plethora of biological functions, yet precision tools for modulating its intracellular flux remain scarce. Conventional small-molecule donors and enzymatic systems often suffer from off-...
Regio- and Diastereoselective Aminopyridylation of Bicyclo[1.1.0]butanes with N‑Aminopyridinium Ylides Enabled by Photoredox Catalysis [0.03%]
光氧化还原催化下N-氨基吡啶
Peng-Fei Chen,Mei-Ling Chen,Zhexuan Lei et al.
Peng-Fei Chen et al.
Visible-light-mediated functionalization of bicyclo[1.1.0]-butanes (BCBs) has been proven to be an efficient way to obtain diverse cyclobutane derivatives. However, achieving diastereoselective control in this field remains challenging. Her...
Helix Regulation of Poly(phenylacetylene)s through the Interplay between Enantiomeric Excess and Temperature-Triggered Pendant Isomerization [0.03%]
手性 excess与温度触发的侧链异构化相互作用调控螺环聚苯乙炔类聚合物立体规整性的研究
Di Wang,Wei Li,Junjie Cheng et al.
Di Wang et al.
The isomerization of pendant groups plays a crucial role in modulating helical structures and biological activity in both biomacromolecule and dynamic helical conjugated polymers. While the effects of solvents, pH, and temperature on pendan...
Juanjuan Jia,Xiangfeng Duan
Juanjuan Jia