Structural Analysis of Tin-Substituted High-Entropy Li-Garnet Electrolytes for Solid-State Batteries [0.03%]
固态电池用Sn取代高熵锂石榴石电解质的结构分析
Benjamin Zimmermann,Till Fuchs,Johannes Westphal et al.
Benjamin Zimmermann et al.
Lithium garnets offer promising structural and electrochemical properties and could be used in all solid-state lithium batteries replacing liquid electrolytes. They can operate in a wide electrochemical voltage window and show high ionic co...
Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions [0.03%]
红光和超硅烷：氢官能团化和盖斯反应的新途径
Aakanksha Gurawa,Marc Taillefer,Alexis Prieto
Aakanksha Gurawa
Herein, we describe the photoredox activation of silanes under deep-red irradiation with or without osmium-based photocatalysts to generate silyl radicals. These radicals were further employed for achieving various reactivities previously u...
The Acidity of Weak NH Acids: Expanding the p K a Scale in Acetonitrile [0.03%]
弱NH酸的酸性：扩大乙腈中pK_a值标度
Märt Lõkov,Carmen Kesküla,Sofja Tshepelevitsh et al.
Märt Lõkov et al.
Nitrogen heterocycles and aromatic amines are well-known and widely used compounds that are usually not seen as acids, although in organic solvents like acetonitrile (MeCN) or dimethyl sulfoxide (DMSO) their acidic properties can be observe...
N-Heterocyclic Carbene-Borane Adducts with Chiral (R)-Chloroethyl and Vinyl Substituents [0.03%]
含手性(R)氯乙基和乙烯基取代基的N-杂环卡宾硼烷加合物
Germán Rodríguez-López,Tayde O Villaseñor-Granados,Sonia Sánchez-Ruiz et al.
Germán Rodríguez-López et al.
This research provides how chiral imidazolium salts {1,3-bis[1'-chloro-1'-phenylpropan-2'-yl]-imidazolium} (1a) and enantiopure {1,3-bis[(R)-1-chlorobutan-2-yl]-imidazolium} [1b] can be utilized in diverse synthetic pathways to obtain new c...
Rearrangement Cascade Initiated by Nucleophilic Benzyne Attack on 3,6-Di(2-pyridyl)-1,2-diazines [0.03%]
2-吡啶基二氮杂稳定碳正离子与苯炔亲核试剂的重排反应
Johannes Schöntag,Theresa Hettiger,William Roberts et al.
Johannes Schöntag et al.
Aryne intermediates in synthetic organic chemistry offer versatile routes to complex heterocyclic structures that are valuable in pharmaceuticals and materials science. We present a one-step aryne-mediated reaction to synthesize pyrido[1,2-...
Paul D Goring,Amelia Newman,Christopher W Jones et al.
Paul D Goring et al.
Strategic Methodologies for Efficient Synthesis of Imidazo[1,5- a]pyridine and Benzazepine Analogs via the Unique Ritter-Type Reaction [0.03%]
一种独特的Ritter型反应高效合成咪唑并吡啶和苯氮杂卓类似物的策略及方法学研究
Gunniga Tanomsiri,Suthimon Boonmee,Nattawadee Chaisan et al.
Gunniga Tanomsiri et al.
We have developed novel approaches for synthesizing imidazo[1,5-a]pyridine and benzazepine analogs through a Ritter-type reaction. These methods utilize bismuth(III) trifluoromethanesulfonate (Bi(OTf)3), an efficient catalyst for converting...
One-Pot NIS-Promoted Cyclization/Palladium-Catalyzed Carbonylation for the Selective Synthesis of HFIP Ester-Containing Indenes and Thiochromenes [0.03%]
一步NIS促进环化/钯催化酰基化选择性合成HFIP酯含邻位茚和噻色满类化合物
Pengfei Ji,Xing-Feng Pan,Xinxin Qi et al.
Pengfei Ji et al.
Practical and atom-economic procedures for the selective synthesis of HFIP ester-containing indenes/thiochromenes from the same propargylic thioethers and HFIP have been developed via one-pot NIS-promoted cyclization/palladium-catalyzed car...
Ali Azmy,Alissa Brooke Anderson,Mina Bagherifard et al.
Ali Azmy et al.
Metal halide semiconductors (MHS) are a versatile class of materials with fully customizable mechanical and optoelectronic properties that have proven to be prominent candidates in numerous impactful applications. Finding a way to generate ...
Abhijit Nayek,Rabin Kumar Poria,Md Estak Ahmed et al.
Abhijit Nayek et al.
Synthetic azadithiolate-bridged diiron clusters serve as structural analogues of the active site of [FeFe]-hydrogenases. Recently, an o-alkyl substitution of aniline-based azadithiolate bridge allowed these synthetic models to both oxidize ...