Tuning the Electronic and Molecular Structures of Bioinspired Heterodinuclear NiFe Catalyst for Enhanced Catalytic H2 Evolution
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With the aim of enhancing the HER activity of the previously described bioinspired [NiFe]-hydrogenase complex [LN2S2NiIIFeIICp-(CO)]+ (LNiFe, with LN2S2 = 2,2'-(2,2'-bipyridine-6,6'-diyl)-bis-(1,1'-diphenylethanethiolate) and Cp = cyclopentadienyl), the el... ...
