Electrocatalytic Behavior of Tetrathiafulvalene (TTF) and Extended Tetrathiafulvalene (exTTF) [FeFe] Hydrogenase Mimics [0.03%]
四硫富瓦烯(TTF)和扩展四硫富瓦烯(exTTF)[铁铁]氢化酶模拟物的电催化行为
Alejandro Torres,Alba Collado,Mar Gómez-Gallego et al.
Alejandro Torres et al.
TTF- and exTTF-containing [(μ-S2)Fe2(CO)6] complexes have been prepared by the photochemical reaction of TTF or exTTF and [(μ-S2)Fe2(CO)6]. These complexes are able to interact with PAHs. In the absence of air and in acid media an electro...
Influence of the CH/B replacement on the Reactivity of Boranthrene and Related Compounds [0.03%]
CH/B置换对硼抗泛素和相关化合物反应性的影响
Iván Cortés,Jorge Juan Cabrera-Trujillo,Israel Fernández
Iván Cortés
The influence of the replacement of CH groups by boron atoms on the reactivity of planar polycyclic aromatic hydrocarbons has been explored by means of computational tools. To this end, [4 + 2]-cycloaddition reactions involving anthracene a...
Géraldine Masson
Géraldine Masson
Zhilin Liang,Midori Amano Patino,Mylène Hendrickx et al.
Zhilin Liang et al.
The progress of the topochemical reduction reaction that converts LaSrNiRuO6 into LaSrNiRuO4 depends on the synthesis conditions used to prepare the oxidized phase. Samples of LaSrNiRuO6 that have been quenched from high temperature can be ...
Cu(I)-azidopyrrolo[3,2- d]pyrimidine Catalyzed Glaser-Hay Reaction under Mild Conditions [0.03%]
温和条件下克来泽-海反应的研究进展：1,4-偶极子环化还是交叉偶联？
Arun K Thangarasu,Velickakathu O Yadhukrishnan,K A Krishnakumar et al.
Arun K Thangarasu et al.
The limitation of the CuAAC "click" reaction with a 2-azidopyridine substrate, owing to its equilibrium with a tetrazole isomer, is exploited herein for its utility in the Glaser-Hay reaction. A catalytic combination of a 2-azidopyridine an...
Photomicellar Catalyzed Synthesis of Amides from Isocyanides: Optimization, Scope, and NMR Studies of Photocatalyst/Surfactant Interactions [0.03%]
光微乳液催化的异氰化物合成酰胺的研究：优化、应用范围和 photocat/NMR 研究
Rolando Cannalire,Federica Santoro,Camilla Russo et al.
Rolando Cannalire et al.
The merging of micellar and photoredox catalysis represents a key issue to promote "in water" photochemical transformations. A photomicellar catalyzed synthesis of amides from N-methyl-N-alkyl aromatic amines and both aliphatic and aromatic...
Straightforward Synthesis of Indenes by Gold-Catalyzed Intramolecular Hydroalkylation of Ynamides [0.03%]
金催化内炔酰胺分子内氢烷基化直接合成吲哚类化合物
Pierre Thilmany,Alejandro Guarnieri-Ibáñez,Clément Jacob et al.
Pierre Thilmany et al.
An original and straightforward entry to polysubstituted indenes from readily available ynamides is reported. Upon reaction with a N-heterocyclic carbene-gold complex under mild conditions, activated keteniminium ions are generated whose un...
Shape Control of MAX Phases by Biopolymer Sol-Gel Synthesis: Cr2GaC Thick Films, Microspheres, and Hollow Microspheres [0.03%]
生物聚合物溶胶-凝胶合成控制MXenes形貌：Cr2GaC厚膜，微球和中空微球
Jan P Siebert,Matthew Flores,Christina S Birkel
Jan P Siebert
The class of MAX phases represents intriguing materials, as they combine ceramic and metallic properties quite exotically. Although many potential areas of application have been identified, a commercialization is still to be realized. This ...
Florian R Neururer,Konstantin Huter,Michael Seidl et al.
Florian R Neururer et al.
We report the facile synthesis of a rare niobium(V) imido NHC complex with a dianionic OCO-pincer benzimidazolylidene ligand (L 1 ) with the general formula [NbL 1 (N t Bu)PyCl] 1-Py. We achieved this by in situ deprotonation of the corres...
Solvent Free Upgrading of 5-Hydroxymethylfurfural (HMF) with Levulinic Acid to HMF Levulinate Using Tin Exchanged Tungstophosphoric Acid Supported on K-10 Catalyst [0.03%]
负载于K-10沸石上的锡交换杂多酸促进5-羟甲基糠醛与醋酮缩合制备5-呋喃甲醛醋酸酯的无溶剂法研究
Manishkumar S Tiwari,Dipti Wagh,Jennifer Sarah Dicks et al.
Manishkumar S Tiwari et al.
The manufacture of high-value products from biomass derived platform chemicals is becoming an integral part of the biorefinery industry. In this study, we demonstrate a green catalytic process using solvent free conditions for the synthesis...