Inverse Photoemission Spectroscopy of Coinage Metal Corroles: Comparison with Solution-Phase Electrochemistry [0.03%]
基于_coinage_金属的冠醚的逆光电子 spectroscopy_:与溶液电化学行为的对比研究
Luca Giovanelli,Younal Ksari,Hela Mrezguia et al.
Luca Giovanelli et al.
A combined direct and inverse photoemission study of coinage metal corroles suggests that the latter technique, in favorable cases, can provide some additional information relative to electrochemical measurements. Thus, whereas inverse phot...
The Persistence of Hydrogen Bonds in Pyrimidinones: From Solution to Crystal [0.03%]
嘧啶酮中氢键的持久性：从溶液到晶体
Fellipe F S Farias,Mateus Mittersteiner,Amanda M Kieling et al.
Fellipe F S Farias et al.
Pyrimidinone scaffolds are present in a wide array of molecules with synthetic and pharmacological utility. The inherent properties of these compounds may be attributed to intermolecular interactions analogous to the interactions that molec...
Corina Stoian,Fawaz Al Hussein,Wesley R Browne et al.
Corina Stoian et al.
From a fundamental perspective, studies of novel mixed-valent complexes containing ferrocenyl units are motivated by the prospect of improving and extending electron transfer models and theories. Here, the series of triferrocenylpnictogens ...
Controlling Redox and Wirelike Charge-Delocalization Properties of Dinuclear Mixed-Valence Complexes with MCp*(dppe) (M = Fe, Ru) Termini Bridged by Metalloporphyrin Linkers [0.03%]
具有MCp*(dppe)（M=Fe，Ru）端基的金属洛合物通过金属洛丁啉连接体控制二核混合价体系中的氧化还原和类线型电荷离域性质
Masahito Murai,Masanori Ono,Yuya Tanaka et al.
Masahito Murai et al.
Four dinuclear organometallic molecular wire complexes with diethynylmetalloporphyrin linkers 1 MM' , [5,15-bis{MCp*(dppe)ethynyl}-10,20-diarylporphinato]M' (Cp* = η5-C5Me5; dppe = 1,2-bis(diphenylphosphino)ethane; M/M' = Fe/Zn (1 FeZn ), ...
Direct Organocatalytic Chemoselective Synthesis of Pharmaceutically Active 1,2,3-Triazoles and 4,5'-Bitriazoles [0.03%]
直接有机催化化学选择性合成药物活性1,2,3-三唑和4,5'-双三唑化合物
Badaraita Gorachand,Gundam Surendra Reddy,Dhevalapally B Ramachary
Badaraita Gorachand
Carbonyl-containing 1,4,5-trisubstituted- and 1,4-disubstituted-1,2,3-triazoles are well-known for their wide range of applications in pharmaceutical and medicinal chemistry, but their high-yielding metal-free synthesis has always remained ...
Easy Access to Fused Tricyclic Quinoline Derivatives through Metal-Free Electrocatalytic [4 + 2] Annulation [0.03%]
无需金属的电催化[4+2]环加成高效构建融合三环喹啉衍生物的新方法
Sayan Ghosh,Samrat Mallick,Devika Karolly et al.
Sayan Ghosh et al.
An efficient electrocatalytic cycloaddition approach for the construction of a lactone- or lactam-fused quinoline framework is documented. Diverse arrays of functionalities are well-compatible under this metal-free, mild, and scalable elect...
Fluorescence Labeling of Peptides: Finding the Optimal Protocol for Coupling Various Dyes to ATCUN-like Structures [0.03%]
ATCUN类似结构与各类荧光染料偶联的最佳方法研究
Jordi C J Hintzen,Shitanshu Devrani,Andrew J Carrod et al.
Jordi C J Hintzen et al.
Labeling of peptides and proteins with fluorescent dyes is a key step in functionalizing these structures for a wide array of biological assays. However, coupling strategies of such dyes have not been optimized for the most common compounds...
Maisa Faour,Karam Yassin,Dario R Dekel
Maisa Faour
Anion-exchange membranes (AEMs), known for enabling the high conductivity of hydroxide anions through dense polymeric structures, are pivotal components in fuel cells, electrolyzers, and other important electrochemical systems. This paper u...
Diversification of Bipyridines and Azaheterocycles via Nucleophilic Displacement of Trimethylammoniums [0.03%]
三甲胺𬭩的亲核取代反应生成双吡啶和氮杂杂环类化合物
Jenny Y Yang,Ryan P King
Jenny Y Yang
Bipyridines and azaarenes are an important class of ligands that impart unique and tunable properties to transition metal complexes and catalysts. While some derivatives are commercially available, noncommercial analogues are often challeng...
Beyond Traditional Synthesis: Electrochemical Approaches to Amine Oxidation for Nitriles and Imines [0.03%]
超越传统合成：用于腈和亚胺的胺氧化的电化学方法
Zhining Xu,Ervin Kovács
Zhining Xu
The electrochemical oxidation of amines to nitriles and imines represents a critical frontier in organic electrochemistry, offering a sustainable pathway to these valuable compounds. Nitriles and amines are pivotal in various industrial app...