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Controlling Redox and Wirelike Charge-Delocalization Properties of Dinuclear Mixed-Valence Complexes with MCp*(dppe) (M = Fe, Ru) Termini Bridged by Metalloporphyrin Linkers

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Four dinuclear organometallic molecular wire complexes with diethynylmetalloporphyrin linkers 1 MM' , [5,15-bis{MCp*(dppe)ethynyl}-10,20-diarylporphinato]M' (Cp* = η5-C5Me5; dppe = 1,2-bis(diphenylphosphino)ethane; M/M' = Fe/Zn (1 FeZn ), Ru/Zn (1 RuZn ), Fe/... ...