Magnetic hysteresis and strong ferromagnetic coupling of sulfur-bridged Dy ions in clusterfullerene Dy2S@C82 [0.03%]
硫桥接镝离子的磁滞和强铁磁耦合行为：Dy₂S@C₈₂簇富勒烯体系中的观测与理论研究
Denis Krylov,Georgios Velkos,Chia-Hsiang Chen et al.
Denis Krylov et al.
Two isomers of metallofullerene Dy2S@C82 with sulfur-bridged Dy ions exhibit broad magnetic hysteresis with sharp steps at sub-Kelvin temperature. Analysis of the level crossing events for different orientations of a magnetic field showed t...
Hydrogen Peroxide Disproportionation with Manganese Macrocyclic Complexes of Cyclen and Pyclen [0.03%]
含锰大环类配合物cyclen和pyclen的过氧化氢歧化反应
David M Freire,Debora Beeri,Kristof Pota et al.
David M Freire et al.
The catalase family of enzymes, which include a variety with a binuclear manganese active site, mitigate the risk from reactive oxygen species by facilitating the disproportionation of hydrogen peroxide into molecular oxygen and water. In t...
CdS Aerogels as Efficient Photocatalysts for Degradation of Organic Dyes under Visible Light Irradiation [0.03%]
CdS气凝胶在可见光照射下降解有机染料的高效光催化剂性能研究
Lasantha Korala,Jason R Germain,Erica Chen et al.
Lasantha Korala et al.
Synthesis of efficient photocatalysts based on CdS nanomaterials for oxidative decomposition of organic effluents typically focuses on (a) enhancement of surface area of the catalysts and (b) promotion of the separation of photogenerated el...
Size Effect of the Active Sites in UiO-66-Supported Nickel Catalysts Synthesized via Atomic Layer Deposition for Ethylene Hydrogenation [0.03%]
原子层沉积负载UiO-66支撑镍催化剂活性位点的尺寸效应及其对乙烯加氢反应性能的影响研究
Zhanyong Li,Aaron W Peters,Jian Liu et al.
Zhanyong Li et al.
Ni(II) ions have been deposited on the Zr6 nodes of a metal-organic framework (MOF), UiO-66, via an ALD-like process (ALD = atomic layer deposition). By varying the number of ALD cycles, three Ni-decorated UiO-66 materials were synthesized....
Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions [0.03%]
在环境条件下快速合成氧化还原活性十二硼烷B12(OR)12簇合物
Alex I Wixtrom,Yanwu Shao,Dahee Jung et al.
Alex I Wixtrom et al.
We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the closo-[B12(OH)12]2- icosahedral dodecaborate cluster via microwave-assisted synthesis. These icosahedral boron cluster...
Luminescent iminophosphorane gold, palladium and platinum complexes as potential anticancer agents [0.03%]
含金、钯和铂的发光亚氨基磷烷配合物作为潜在的抗癌剂
Malgorzata Frik,Josefina Jiménez,Vadim Vasilevski et al.
Malgorzata Frik et al.
A series of coordination gold(III), palladium(II), and platinum(II) complexes with a luminescent iminophosphorane ligand derived from 8-aminoquinoline [Ph3P=N-C9H6N] (1), have been synthesized and structurally characterized. The coordinatio...
Ambika Bhagi-Damodaran,Yi Lu
Ambika Bhagi-Damodaran
Methane monooxygenases (MMOs) activate the high energy C-H bond of methane and convert it to methanol with high selectivity and under physiological conditions. Despite decades of efforts focusing on elucidating the structure, function and m...
Modulating the Copper-Sulfur Interaction in Type 1 Blue Copper Azurin by Replacing Cys112 with Nonproteinogenic Homocysteine [0.03%]
通过用非蛋白源同型半胱氨酸替换半胱氨酸112来调节I型蓝铜素藻红蛋白中的铜-硫相互作用
Kevin M Clark,Yang Yu,Wilfred A van der Donk et al.
Kevin M Clark et al.
The Cu-SCys interaction is known to play a dominant role in defining the type 1 (T1) blue copper center with respect to both its electronic structure and electron transfer function. Despite this importance, its role has yet to be probed by ...