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Size Effect of the Active Sites in UiO-66-Supported Nickel Catalysts Synthesized via Atomic Layer Deposition for Ethylene Hydrogenation

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Ni(II) ions have been deposited on the Zr6 nodes of a metal-organic framework (MOF), UiO-66, via an ALD-like process (ALD = atomic layer deposition). By varying the number of ALD cycles, three Ni-decorated UiO-66 materials were synthesized. A suite of physical... ...