Activation of a water molecule using a mononuclear Mn complex: from Mn-aquo, to Mn-hydroxo, to Mn-oxyl via charge compensation [0.03%]
锰单核配合物活化水分子：从Mn-亚 aquo到Mn-羟基再到通过电荷补偿的Mn-氧基自由基
Benedikt Lassalle-Kaiser,Christelle Hureau,Dimitrios A Pantazis et al.
Benedikt Lassalle-Kaiser et al.
Activation of a water molecule by the electrochemical oxidation of a Mn-aquo complex accompanied by the loss of protons is reported. The sequential (2 × 1 electron/1 proton) and direct (2 electron/2 proton) proton-coupled electrochemical o...
Charge Photo-Accumulation and Photocatalytic Hydrogen Evolution Under Visible Light at an Iridium(III)-Photosensitized Polyoxotungstate [0.03%]
可见光下铱(III)敏化多金属氧酸盐的电荷积累及光电催化产氢
Benjamin Matt,Jennifer Fize,Jamal Moussa et al.
Benjamin Matt et al.
Steady-state irradiation under visible light of a covalent Ir(III)-photosensitized polyoxotungstate is reported. In the presence of a sacrificial electron donor, the photolysis leads to the very efficient photoreduction of the polyoxometala...
METABOLIC SPATIAL VARIABILITY IN ELECTRODE-RESPIRING GEOBACTER SULFURREDUCENS BIOFILMS [0.03%]
受电极呼吸影响的Geobacter sulfurreducens生物膜代谢空间差异性
Rs Renslow,Jt Babauta,A Dohnalkova et al.
Rs Renslow et al.
In this study, we quantified electron transfer rates, depth profiles of electron donor, and biofilm structure of Geobacter sulfurreducens biofilms using an electrochemical-nuclear magnetic resonance microimaging biofilm reactor. Our goal wa...
Rs Renslow,Jt Babauta,Pd Majors et al.
Rs Renslow et al.
The goal of this study was to measure spatially and temporally resolved effective diffusion coefficients (D(e)) in biofilms respiring on electrodes. Two model electrochemically active biofilms, Geobacter sulfurreducens PCA and Shewanella on...