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Charge Photo-Accumulation and Photocatalytic Hydrogen Evolution Under Visible Light at an Iridium(III)-Photosensitized Polyoxotungstate

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Steady-state irradiation under visible light of a covalent Ir(III)-photosensitized polyoxotungstate is reported. In the presence of a sacrificial electron donor, the photolysis leads to the very efficient photoreduction of the polyoxometalate. Successive forma... ...