Full-Dimensional Control of Covalent Organic Frameworks Through Repulsion-Torsion Effect: Prominent 1D Above 2D and 3D Structures [0.03%]
通过排斥-扭转效应实现共价有机框架的全维度调控：突出的一维超越二维和三维结构
Kaifu Yu,Pan He,Dong Zhang et al.
Kaifu Yu et al.
Exploring the impact of different dimensions on the properties and functions of covalent organic frameworks (COFs) has always been a key goal, as this can provide feedback to assist in the design of advanced COFs. However, this goal has nev...
Supramolecular Engineering of Cluster-Assembled Materials for Amplification and Dynamic Modulation of Chiral Luminescence [0.03%]
超分子工程组装簇诱导的手性放大及动态调控发光研究
Camelia Dutta,Anannya Mandal,Abhishek Shukla et al.
Camelia Dutta et al.
Chiral metal clusters have garnered significant research interest in recent years due to their unique photophysical and chiroptical properties. Increased attention is directed toward bimetallic systems, as the synergistic effect of two diff...
Spin-Orbit Effects in a Thallium Borohydride Stabilized by Coordination to Bis(diisopropylamino)Cyclopropenylidene (BAC) [0.03%]
稳定的三价金丝元素硼氢化物中的自旋-轨道效应（与BAC配体配位）
Thien H Nguyen,Xiaojuan Yu,Guang Wu et al.
Thien H Nguyen et al.
Reaction of Tl(OTf) with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) in THF results in formation of [Tl(BAC)2(OTf)] (1) in moderate yields. Subsequent reaction of 1 with [K][H2-9-BBN] ([H2-9-BBN]- = dihydrido 9-boratabicyclo[3....
Pyridine Nitrogen Decorated Carbon Support for High-Performance Seawater Electrolyte-Based Zinc-Air Battery [0.03%]
用于高性能海水系锌空气电池的吡啶氮修饰碳载氧还原反应催化剂
Yurong Liu,Yousheng Zhu,Yuxin Zhang et al.
Yurong Liu et al.
Developing high specific energy seawater electrolyte-based zinc-air batteries (SZABs) is crucial for marine energy supply systems. However, their widespread application is restricted by the slow oxygen reduction reaction (ORR) kinetics coup...
Electrochemical Alkyl Displacement of Thioethers for Streamlined Trideuteromethylation [0.03%]
硫醚的电化学烃基置换实现简洁的三氘代甲基化
Hongshuai Chen,Yanghao Yin,Guoqing Wang et al.
Hongshuai Chen et al.
Deuterated compounds exhibit significant pharmacokinetic advantages and have been widely applied in drug discovery. Trideuteromethyl-containing compounds represent a substantial portion of both approved deuterated drugs and those in develop...
Efficient Hydrogen Sulfide Separation from Carbon Dioxide Achieved by Carbonyl-Functionalized Ionic Liquids for Natural Gas Upgrading [0.03%]
应用于天然气提纯的羰基官能团离子液体高效脱除二氧化碳中的硫化氢
Mingzhen Shi,Guoao Li,Hangzhi Wu et al.
Mingzhen Shi et al.
Natural gas upgrading requires efficient separation of H2S from CO2, another acidic impurity, to enhance gas utilization efficiency and enable resource recovery from waste streams. While significant advancements have been achieved in separa...
Chloromethoxytrityls: Tuning the SOMO Level of Stable Luminescent Radicals [0.03%]
氯甲氧基三苯甲基：稳定发光自由基的SOMO调优
Hannah E Hackney,Cory Ruchlin,Emil Stahle et al.
Hannah E Hackney et al.
Luminescent radicals are of significant recent interest because of the unique quantum properties of the doublet excited state. Control of the energy level of the singly-occupied molecular orbital (SOMO) is essential for the design and appli...
pH-Dependent Packing Mode Variations and Chirality Inversion in Short Peptide Self-Assembly [0.03%]
短肽自组装中的pH依赖性堆积模式变化与手性翻转现象
Xiaoyue Ma,Kai Qi,Xinfeng Ju et al.
Xiaoyue Ma et al.
Precise control of structures and morphologies in peptide self-assembly has been challenging. We report the self-assembly of amphiphilic peptides I3H, designed with a modular structure featuring three consecutive isoleucine residues as a hy...
Feedstock-Derived Thiophene Radical Anions Exhibiting Redox Stability at Extreme Potentials [0.03%]
具有极端电位下氧化还原稳定性的含硫苯基自由基阴离子及其制备方法和应用
Aurelio C Gasser,Daniel Käch,Máté J Bezdek
Aurelio C Gasser
Organic radicals that are both readily synthesized from commodity chemicals and stable at extreme redox potentials are rare, yet highly desirable for applications in energy storage and organic electronics. Herein, we report feedstock-derive...