Spin-Orbit Effects in a Thallium Borohydride Stabilized by Coordination to Bis(diisopropylamino)Cyclopropenylidene (BAC)
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Reaction of Tl(OTf) with 2 equiv of bis(diisopropylamino)cyclopropenylidene (BAC) in THF results in formation of [Tl(BAC)2(OTf)] (1) in moderate yields. Subsequent reaction of 1 with [K][H2-9-BBN] ([H2-9-BBN]- = dihydrido 9-boratabicyclo[3.3.1]nonane) in THF r... ...
