Enzymatic Flow Electrolyzer for CO2 and Waste Comproportionation to Formate and Its Use in Photocatalytic Alkene Hydrocarboxylation [0.03%]
用于生成甲酸的二氧化碳和废物复合比例电解装置及其在光催化烯烃羟基羧基化的应用
Beverly Q L Low,Santiago Rodríguez-Jiménez,Andrea Rogolino et al.
Beverly Q L Low et al.
Paired electrolysis enables the simultaneous coupling of CO2 reduction with anodic waste upcycling to form valuable products. However, achieving selective, efficient, and stable product formation and coupling to downstream valorization rema...
Localizing the Long-Range Disorder of Reconstructed Cobalt Oxyhydroxides for Anion Exchange Membrane Water Electrolysis [0.03%]
用于阴离子交换膜水电解的重建氢氧化钴长程无序的局域化
Jingxuan Zhao,Kunjie Wang,Xiangyang Li et al.
Jingxuan Zhao et al.
Controlling the long-range disorder of dynamically reconstructed nanostructures represents a challenging but important approach for achieving practical catalysts with high performance. Here, we report a facile fluoride-mediated-stabilizatio...
Quantum Interference Effect in Saturated Systems: Effect of Anchoring Group Position on Conductance of Bipiperidines and their in-situ Derived Dithiocarbamates [0.03%]
饱和体系中的量子干涉效应：固定基团位置对双哌啶及其原位生成的二硫代氨基甲酸盐导电性的影响
Umar Rashid,Abdalghani H S Daaoub,P A Sreelakshmi et al.
Umar Rashid et al.
This study investigates quantum interference in σ-only molecular systems, focusing on the impact of anchoring group nature and its position. Using a combined approach of mechanically controlled break junction experiments and quantum transp...
Emerging Nitroso/Hydroxylamine Redox Chemistry for High-Performance Organic Cathodes in Aqueous Proton Batteries [0.03%]
用于 proton 水系电池的高性能有机正极中的硝基/羟胺类化合物红氧化学反应的新进展
Jiapeng Zhao,Yuxin Xue,Yisan Shen et al.
Jiapeng Zhao et al.
Organic cathode materials are emerging candidates for aqueous proton batteries due to their structural tunability and sustainability. However, the simultaneous realization of high voltage, low solubility, and high capacity remains a major c...
Sequence-Specific Installation of Aryl Groups in RNA via DNA-Catalyst Conjugates [0.03%]
基于DNA-催化剂缀合物在RNA中进行特定位点的芳基化反应
Sumon Pratihar,Wenrui Zhong,Sheng Feng et al.
Sumon Pratihar et al.
Installing functional groups at specific sites in existing RNA molecules remains a challenge for modification, labeling, and therapeutic strategies. Here, we describe the use of DNA oligonucleotides carrying a catalytic amine group to effec...
Reverse Modulation of Carbon-Interface Electron Density via s-d Block High-Entropy-Alloys Boosts Li-S Batteries [0.03%]
通过s-d杂化高熵合金逆向调节碳界面电子密度提升锂硫电池性能
Yanjuan Li,Qingzhao Chen,Zhanzhan Wang et al.
Yanjuan Li et al.
Carbon materials, renowned for their exceptional intrinsic properties, play a pivotal role in the domain of lithium-sulfur batteries, especially for encasing delicate metal-based catalysts. However, this encasement hinders the precise contr...
Dual-Channel Gas-Sensitive Fluorescent Switch: Realizing a Reversible Fluorescent Response to HCl and NH3 [0.03%]
双通道气体敏感荧光开关：实现HCl和NH3的可逆荧光响应
Shuyu Wang,Qianhong Fan,Lei Wang et al.
Shuyu Wang et al.
Luminescent metal-organic frameworks (LMOFs) provide exceptional advantages over conventional materials in detecting harmful gases. However, challenges remain, such as limited stability, unclear fluorescence signal changes and insufficient ...
Responsible Use of Kinematic Models: Correspondence on "Navigating Ball Mill Specifications for Theory-to-Practice Reproducibility in Mechanochemistry" [0.03%]
关于“机械化学理论实践再现性的球磨机规格导航”的通信：动力学模型的负责任使用
Gregory I Peterson
Gregory I Peterson
In their recent article, Jafter et al. present "refined" kinematic models for planetary and mixer mills. While the improvement of such models is a valuable pursuit, we find that aspects of the presentation and application of these models ra...
Structural Tweaking of Zwitterionic Metallosupramolecular Assemblies for Intense NIR Emission and High Charge Carrier Mobility [0.03%]
通过结构微调具有强烈近红外发射和高载流子迁移率的两性离子金属超分子组装体
Divya Susan Philips,Samrat Ghosh,Akinori Saeki et al.
Divya Susan Philips et al.
Metal organic materials (MOMs) with intense NIR emission and charge transport are essential for biomedical and bioelectronic applications, particularly in devices for medical diagnostics. Metallosupramolecular assemblies guided by direction...
Reversing Lanmodulin's Metal-Binding Sequence in Short Peptides Surprisingly Increases the Lanthanide Affinity [0.03%]
令人惊讶的是，在短肽中逆转Lanmodulin的金属结合序列可以增加镧系元素的亲和力
Sophie M Gutenthaler-Tietze,Jerome Kretzschmar,Satoru Tsushima et al.
Sophie M Gutenthaler-Tietze et al.
Rare earth elements (REEs) are essential for a clean energy future, high tech, and medicine. For these applications the chemically similar elements need to be tediously separated. Recent discoveries that specific lanthanide-binding proteins...