Kecheng Huang,Ran Meng,Bei Li et al.
Kecheng Huang et al.
Cancer is a complicated disease driven by multiple etiologies, necessitating urgent, multimodal, and integrated therapeutic strategies. Coined just over a decade ago, metal-phenolic networks (MPNs) have emerged as broad and powerful platfor...
Spiro[16]arene: A Spirocycle-Bridged Macrocycle With Nanocarbon Recognition [0.03%]
螺[16]环烃：一种识别纳米碳的手臂连接大环化合物
Yifei Zhang,Kailin Hu,Yu Zhou et al.
Yifei Zhang et al.
The development of new bridging chemistry for macrocyclic arenes is crucial for creating supramolecular hosts with well-defined structures and practical functions. In this work, we report a spirocycle-bridged macrocycle named spiro[16]arene...
Thomas Tilger,Esther Ohnesorge,Hayden Robertson et al.
Thomas Tilger et al.
Electrostatic interactions in soft matter and physical chemistry are fundamentally governed by the size and charge of the interacting species. The two polyoxometalates (POMs) with the Keggin structure phosphotungstate [ PW 12 O 40 ] 3 - ...
Solvation-Hierarchy Electrolyte for Balancing Kinetics and Stability in Sodium-Sulfur Batteries [0.03%]
分层次溶剂化结构电解质实现钠硫电池动力学和稳定性的平衡
Ao Zhong,Jiang Liang,Kangning Zhao et al.
Ao Zhong et al.
Room-temperature sodium-sulfur batteries hold immense promise for next-generation energy storage, while hindered by the dilemma of sodium polysulfide (NaPS) shuttling and redox kinetic. Here, we propose a solvation hierarchy strategy for so...
Supramolecular Chiral Halogen-Bonded Organic Frameworks Enhance Efficient Chirality-Induced Spin Selectivity [0.03%]
超分子手性卤素键有机框架增强高效手性诱导自旋选择性
Congcong Zhang,Zhongchen Xu,Siyi Lin et al.
Congcong Zhang et al.
Chirality-induced spin selectivity (CISS) has attracted extensive interest for its various potential applications. However, the development of high-spin-polarization CISS materials still represents a significant challenge. We report the des...
Site-Selective Dearomative [2+2] Photocycloaddition of Naphthalene Derivatives With Alkenes [0.03%]
萘衍生物与烯烃的去芳构化[2+2]光环加成反应选择性 sites
Muzi Li,Ruihua Pu,Zhe-Qi Wang et al.
Muzi Li et al.
Photocycloaddition between aromatics and alkenes is a fundamental class of reactions in organic chemistry. Conventional approaches have predominantly harnessed triplet-state manifolds to achieve [4+2] cycloadditions. However, reversing the ...
Constructing Substituted-Pyridine-Linked Conjugated Porous Polymers via Multicomponent Hantzsch-Type Reaction for Efficient Hydrogen Peroxide Photosynthesis from Real Seawater and Air [0.03%]
通过多组分汉斯奇型反应构建含取代吡啶连接共轭多孔聚合物高效光合成海水和空气中的过氧化氢
Changgui Lv,Jingmin Ge,Xikai Chen et al.
Changgui Lv et al.
Conjugated porous polymers (CPPs) have emerged as promising organo-based semiconducting materials for solar-to-chemical energy conversion due to their customizable structures and functionalities. Exploring diverse synthetic routes provides ...
Precise Energy-Level Engineering of X-Shaped D-A Dyads for 1.16 s Anti-Kasha 3CT Room-Temperature Phosphorescence [0.03%]
X型D-π-A二聚体的精确能级工程实现反卡沙机制室温长寿命三线态激子发射（1.16 s）
Guiyin Luo,Daihe Zhou,Chuanhao Liu et al.
Guiyin Luo et al.
The development of charge-transfer organic room-temperature phosphorescence (3CT-ORTP) materials with second-level lifetime remains a significant challenge. Herein, we report a molecular engineering strategy using X-shaped donor-acceptor (D...
Breakthrough Design of Highly Potent Antivirals Against Wild-Type HIV-1 and Lenacapavir-Resistant M66I Variant [0.03%]
针对野生型HIV-1和Lenacapavir耐药M66I变异体的高效抗病毒新药设计突破
Nicolas Jamey,D M Nirosh Udayanga,Huanchun Zhang et al.
Nicolas Jamey et al.
Lenacapavir (LEN), the first-in-class HIV-1 capsid inhibitor (CAI) with picomolar potency and long pharmacokinetics (PK), is approved for both treatment and pre-exposure prophylaxis (PrEP). However, the frequently selected M66I mutation con...
Spin-Polarized Interfaces Redirect CO2 Reduction From CO to Formate [0.03%]
自旋极化界面调控二氧化碳电还原路径生成一氧化碳和甲酸盐
Fan He,Xingxu Yan,Xiaoqing Pan et al.
Fan He et al.
Achieving high product selectivity in electrocatalytic carbon dioxide reduction (CO2RR) remains a critical challenge due to competition between multiple proton-coupled electron-transfer pathways on catalyst surfaces. Meanwhile, chirality-in...