Redefining the Coordination Mode of 1,2,4-Triazolylidene: Bridging the Gap Between Molecular Organometallic Chemistry and Extended Porous Architectures [0.03%]
重新定义1,2,4-三氮烯的配位模式：分子金属有机化学与扩展多孔结构之间的桥梁关系
Shashi Kumar,Priyadharshini Velmurugan,Arnab Rit
Shashi Kumar
Although molecular organometallic complexes are widely exercised across various chemistry domains, their evolution into extended porous frameworks has been lacking for C-donor NHC ligands. In this study, we present the first such example by...
Imidazolium-Derived Porous Organic Polymer as Robust Platform for Rhodium-Catalyzed N2O Hydrogenation and Alcohol Oxygenation [0.03%]
用于一氧化二氮氢化及醇类氧化的鲁棒型铑催化剂平台——咪唑衍生多孔有机聚合物
Sven Thomas Nappen,Veit Dippold,Darosch Asgari et al.
Sven Thomas Nappen et al.
The catalytic conversion of nitrous oxide, a potent greenhouse gas and ozone-depleting substance, offers a promising strategy for mitigating emissions but requires efficient catalysts that operate under mild conditions. Here, a porous organ...
Jia-Yao Wang,Ming-Di Gao,Chao-Yang Guan et al.
Jia-Yao Wang et al.
Incorporating artificial molecular machines into soft matter offers a compelling strategy for engineering active materials with life-like behavior. Here, we report ultraviolet and visible light-responsive RNA photofluids formed via liquid-l...
Structural Transformation and Photochromism of Chiral Hybrid Metal Halides for Stimulus-Responsive Phosphorescence and Circularly Polarized Luminescence [0.03%]
手性金属卤素配位聚合物的刺激响应式室温磷光和圆偏振发光
Ruo-Yu Zhang,Ni Dan,Jiaojiao Wei et al.
Ruo-Yu Zhang et al.
Chiral organic-inorganic hybrid metal halides (OIMHs) have emerged as promising systems for stimuli-responsive circularly polarized luminescence (CPL). However, chiral OIMHs featuring both photochromic CPL and room temperature phosphorescen...
Modeling Midbrain and Brainstem Neuromelanins to Characterize Metal Binding and Associated MRI Contrast in Parkinson's and Alzheimer's Diseases [0.03%]
帕金森和阿尔茨海默病中铁结合及相关的磁共振成像对比的中脑和延髓色素团模擬研究
Niklas Wallstein,Andrea Capucciati,Andreas Pöppl et al.
Niklas Wallstein et al.
Neuromelanin (NM) is a dark pigment that binds potentially toxic metal ions and is crucial for neuronal vulnerability. Magnetic resonance imaging (MRI) was proposed to measure neuromelanin in the substantia nigra or locus coeruleus, potenti...
Enhanced Emission in Core@Shell Heterostructure of 3D Halide Double Perovskites [0.03%]
三维卤化物双钙钛矿核心@壳异质结构的增强发射
Rachna Singh,Ajeet Singh,Gauri Sharma et al.
Rachna Singh et al.
Inorganic metal halide double perovskites (HDPs) have successfully addressed the toxicity and instability concerns of lead-based perovskites. However, they still have to bridge a significant gap to obtain the desired optical properties. The...
Single-Cell Antimicrobial Susceptibility Testing via Stimulus-Responsive Resonance Raman Scattering Imaging [0.03%]
基于刺激响应型共振拉曼散射的单细胞抗菌药物敏感性检测方法研究
Wenshuai Li,Leilei Yang,Yongmei Yin et al.
Wenshuai Li et al.
Antimicrobial resistance (AMR) has emerged as a formidable worldwide public health crisis. Antimicrobial susceptibility testing (AST), the current gold standard for AMR detection, is essential for guiding antibiotic usage but requires days ...
Concurrent Ferroptosis and Pyroptosis Induced by a Dual-Organelle-Targeted Type I/II AIE Photosensitizer for Bladder Cancer Immunotherapy [0.03%]
一种双靶向I型/II型AIE光敏剂诱导铁死亡和细胞焦亡协同免疫治疗膀胱癌
Yifan Cheng,Kun Zhou,Yuhang Chen et al.
Yifan Cheng et al.
The therapeutic efficacy and cell death modalities of photodynamic therapy (PDT) highly depend on reactive oxygen species (ROS) generation mediated by photosensitizers (PSs) and their subcellular localization. However, research exploring th...
Chiral Nematic Liquid Crystal Films for High-Performance Circularly Polarized Organic Light-Emitting Diodes [0.03%]
手性向列型液晶薄膜在高性能圆偏振有机发光二极管中的应用
Zhen-Xing Yu,Xu-Wei Chen,Chuan-Feng Chen et al.
Zhen-Xing Yu et al.
Circularly polarized organic light-emitting diodes (CP-OLEDs) have emerged as promising candidates for energy-efficient displays and eye-healthy lighting technologies. However, CP-OLEDs obtained from conventional chiral luminescent material...
Nanocellular Organelle Engineering for Optimizing Reaction Microenvironments in Nitrate-to-Ammonia Electrocatalysis [0.03%]
硝酸根电解氨解反应微环境优化的纳米细胞器工程学
Qiang Tian,Xieshu Ye,Lingyan Jing et al.
Qiang Tian et al.
Certain natural catalysts, biological enzymes, tend to be confined within cellular organelles to achieve high catalytic efficiency in small molecule conversion due to the optimized reaction environment within their internal space. Inspired ...