Channel-Pocket Ultra-Micropore Configuration in a Hydrogen-Bonded Organic Framework for Simultaneous High Xe Capture and Xe/Kr Separation [0.03%]
氢键有机框架中通道-笼超强微孔构型的构建用于实现高Xe捕获及Xe/Kr分离
Jia-Xin Wang,Shunshun Xiong,Xiao-Wen Gu et al.
Jia-Xin Wang et al.
Development of energy-efficient physisorbents for xenon/krypton (Xe/Kr) separation is highly essential to produce high-purity noble gases and control the pollution of radioactive isotopes. Porous organic materials are very promising for gas...
Asymmetric Diamine Synthesis for Covalent Organic Frameworks: Boosted Photocatalytic Performance by Restricting β-Ketoenamine Bond Twist [0.03%]
不对称胺合成用于共价有机框架：通过限制β-酮亚胺键的扭折来提高光催化性能
Lichao Wang,Dongge Ma,Aoxiang Liu et al.
Lichao Wang et al.
Covalent organic frameworks (COFs) are typically formed by the covalent bonding of geometrically symmetrical linkers. In this work, an asymmetric (C1h symmetry) amine linker (2,6-diaminobenzothiazole) was employed to non-linearly connect an...
Jacob J. Lessard [0.03%]
雅各布·J·勒萨德
Jacob J Lessard
Jacob J Lessard
"I advise my students to run controls early, fail often, and fail quickly… The most challenging aspect of refereeing is balancing rigor with compassion. The authors have put a lot of work into the manuscript and your job as a referee is to...
Molecular Locking in Triplet Sensitization Amplifies Circularly Polarized Luminescence [0.03%]
三重态敏化中的分子锁定可增强圆偏振发光
Wenfei Liang,Shaokuan Gong,Bo Yang et al.
Wenfei Liang et al.
The potential of chiral organic molecules exhibiting circularly polarized luminescence (CPL) for practical applications hinges on the luminescence efficiency and dissymmetry factor (glum). However, surpassing the molecular limitations of di...
Interrupting the Hydroxide Enrichment-Induced Electrode Degradation Loop for Achieving Stable Aqueous Zn-I2 Batteries [0.03%]
实现稳定水系锌碘电池的打断氢氧化物富集引起的电极降解循环
Hanlin Ding,Zhenxin Lin,Xiaoting Lin et al.
Hanlin Ding et al.
Severe adverse reactions, including hydrogen evolution reaction (HER) and polyiodide shuttle, lead to short lifetimes of rechargeable aqueous zinc-iodine (Zn-I2) batteries and have aroused widespread attention. However, few studies have spe...
Hydrophobic Polymer Zwitterions: Impacts of Silylsilane Substitution on Solution and Interfacial Properties [0.03%]
硅基烷基侧链对两性离子聚合物溶液性质和界面性质的影响研究
Carla G Steppan,Xuchen Gan,Hayden Marquard et al.
Carla G Steppan et al.
A new class of zwitterionic polymer amphiphiles was prepared by synthesis and polymerization of novel silyl-substituted sulfobetaine (SB) methacrylate monomers. These silyl-SB methacrylates proved amenable to controlled free radical polymer...
Polymer Ligands with Quaternary Ammonium Binding Motifs on Metal Nanoparticles Enable Selective Ion Transport for CO2 Electroreduction [0.03%]
金属纳米颗粒上的季铵结合配体使选择性离子运输用于CO2电还原
Debasmita Muhuri,Manthan Sarkar,Hanyi Duan et al.
Debasmita Muhuri et al.
We report a new class of hydrophobic polymer ligands with quaternary ammonium head groups for surface modification of noble metal nanoparticles (NPs). Quaternary ammonium ligands bind NPs through non-covalent electrostatic interactions, pro...
N-Heterocyclic Carbenes on a III-V Semiconductor: From Chain Formation to Ordered Monolayers [0.03%]
III-V半导体上的N-杂环卡宾：从链形成到有序单层结构
Martin Franz,Ankita Das,Sandhya Chandola et al.
Martin Franz et al.
N-Heterocyclic carbenes (NHCs) are established ligands for various surfaces, known for their strong binding, ability to form self-assembled monolayers, and modular structure. However, semiconductor surface modification with NHCs is still in...
Bicyclic Isosteres of Pyridine/Piperidine: From Synthesis to Applications [0.03%]
吡啶/哌啶的双环等体化合物：从合成到应用
Oleksandr Stashkevych,Volodymyr Kokhalskyi,Yevhenii Mynak et al.
Oleksandr Stashkevych et al.
2-Azabicyclo[2.2.2]octanes have been designed, synthesized, and validated biologically as isosteres of piperidine/pyridine. The key reaction step was the cyclization of cyclic alkenyl amines with the KOtBu/I2/CO2 combination. The method pro...
Enantioconvergent Borylation of α-Benzoyl Alkyl Bromides by Zinc Catalysis [0.03%]
手性锌催化剂催化的α-芳甲酰烷基溴𬭩盐的对映汇聚性硼化反应
Huiyang Liu,Xiangyu Zhang,Du Chen et al.
Huiyang Liu et al.
The direct synthesis of chiral compounds from racemic alkyl halides is highly valued in organic synthesis. In this study, we present the first zinc-catalyzed enantioconvergent transformation of alkyl halides, which is enabled by substrate d...