From Solvent to Catalyst: In Situ Amino Acid-Like Species Enable PET Upcycling Without Added Catalysts [0.03%]
从溶剂到催化剂：原位氨基酸-like物质无需添加催化剂即可实现PET升级回收
Xiong Gao,Zhuo Wang,Minghao Zhang et al.
Xiong Gao et al.
Chemical recycling of polyethylene terephthalate (PET) offers a promising route to value-added chemical production, yet conventional methods typically demand harsh conditions and dedicated catalysts. Here, we report a bioinspired strategy t...
Enhancing Cascade Reaction Efficiency by Local pH Regulation for Integrated Anodic H2O2 Generation and Ammoximation [0.03%]
通过局部pH调节增强级联反应效率，实现集成为阳极过氧化氢生成和氨氧化胺化集成反应
Lejing Li,Jian Zhang,Carla Santana Santos et al.
Lejing Li et al.
Cascade reaction strategies integrating electrochemistry with chemical transformations offer routes for the synthesis of value-added chemicals. However, the efficiencies of such integrated processes get compromised due to competitive electr...
Amine-Ligated Boryl Radicals Enables Direct C─F Borylation and Cross-Couplings of Polyfluoroarenes [0.03%]
含胺基配体的硼自由基实现了多氟芳烃的直接C-F键硼化及交叉偶联反应
Naoki Yasukawa,Waka Okada,Marc Fimm et al.
Naoki Yasukawa et al.
Polyfluoroarenes are privileged scaffolds in pharmaceutical and materials science, yet their synthesis remains challenging. Aromatic borylation offers a modular entry point for derivatization via Suzuki-Miyaura cross-coupling, but progress ...
Highly Stable π‑Extended Viologen Functionalized Hybrid Lead Halides for Near Infrared-Driven CO2-to-C2H4 Photoconversion [0.03%]
用于近红外驱动二氧化碳至乙烯光转化的稳定π共轭二茂铁功能化混合型卤素铅材料
Chen Sun,Jinlin Yin,Honghan Fei
Chen Sun
Hybrid lead halides show great potential for CO2 photoreduction owing to their structural tunability and excellent photophysical properties. However, their intrinsic instability and the suppressed efficiency of C-C coupling under near-infra...
Synergic Coordination Effect in Nonflammable Deep Eutectic Electrolyte for High-Performance Sodium-Ion Batteries [0.03%]
用于高性能钠离子电池的非易燃深共熔电解质中的协同协调效应
Ao Xu,Li Zhao,Jingyuan Yu et al.
Ao Xu et al.
Deep eutectic electrolytes (DEEs) are emerging as a highly promising class of next-generation electrolytes, poised to revolutionize the performance of safe sodium-ion batteries (SIBs). Nevertheless, a significant challenge hindering the pro...
James S W Seale,Swagat Sharma,Christopher K Lee et al.
James S W Seale et al.
During the past decade, researchers have designed and synthesised a variety of artificial molecular pumps capable of the active transport of macrocycles (rings) from free solution into mechanically interlocked states. In their ability to dr...
Finding the Key: Binding of Metal-Oxo Clusters to the Enzyme Active Site Enabled by "Click" (Bio)Conjugation [0.03%]
揭秘关键：“点击”型（生物）交联使金属氧化物簇结合至酶活性中心
Givi Kalandia,Kilian Declerck,David E Salazar Marcano et al.
Givi Kalandia et al.
Molecular metal-oxo nanoclusters with tunable redox and structural properties have emerged as powerful bio-inorganic tools in catalysis, protein crystallization, and therapeutic applications. Despite their potential, interactions between di...
Lower Critical Solution Temperature Active Supramolecular π-Systems for Smart Applications [0.03%]
用于智能应用的低临界溶解温度型超分子π体系
Dipak Patra,Rahul Dev Mukhopadhyay,Ayyappanpillai Ajayaghosh
Dipak Patra
Stimuli-responsive supramolecular systems have emerged as an essential requirement for a wide range of smart applications in material sciences and biology. Among various responses, thermal response is a common functional characteristic of m...
Delocalized Frustrated Lewis Pairs in COF-Catalyzed N-Transfer for Urea Photosynthesis [0.03%]
用于尿素光合作用的N-转移的COF催化的离域化 frustrated lewis 对_pairs(_FLPs_)
Haozhen Wang,Lu Song,Mengqiu Xu et al.
Haozhen Wang et al.
Photosynthesis of urea through C─N coupling from CO2 and nitrates (NO3 -) represents a sustainable route for both carbon utilization and environmental remediation, yet remains fundamentally challenging due to competing parallel reduction r...
Zeping Liu,Yu Zhang,Meng Li et al.
Zeping Liu et al.
Aqueous zinc ion batteries are attracting growing interest in electrochemical energy storage due to safety, reliability, and affordability. However, water brings drawbacks including parasitic reactions, narrow electrochemical window, and ca...