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Amine-Ligated Boryl Radicals Enables Direct C─F Borylation and Cross-Couplings of Polyfluoroarenes

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Polyfluoroarenes are privileged scaffolds in pharmaceutical and materials science, yet their synthesis remains challenging. Aromatic borylation offers a modular entry point for derivatization via Suzuki-Miyaura cross-coupling, but progress is hindered by two p... ...