Protein Cage Inspired Bridge-Island Effect Enables Low-Temperature Targeted Self-Assembly of Hierarchical Hollow Polyanionic Cathodes for Sodium-Ion Batteries [0.03%]
受蛋白质笼启发的桥岛效应可在低温下实现分层空心聚阴离子 cathode 钠离子电池的靶向自组装
Shuqiang Li,Xueying Lu,Yu Li et al.
Shuqiang Li et al.
Achieving targeted morphological control over polyanionic cathodes under mild conditions remains a critical challenge. Drawing inspiration from the self-assembly of protein cages, we propose an ionic weaving strategy for the low-temperature...
Broadly Tunable Liquid-State Lasers and Solid-State Single-Longitudinal-Mode Near-Infrared Lasers Utilizing Halogen-Doped Graphene Quantum Dots [0.03%]
用于卤素掺杂石墨烯量子点的宽调谐液体激光器和近红外单纵模固体激光器
Shurong Ding,Haoqiang Song,Yongsheng Hu et al.
Shurong Ding et al.
Understanding the lasing mechanism of graphene quantum dots (GQDs) is crucial for enhancing their gain characteristics and developing high-performance laser devices. In this study, we investigated ultrafast excited-state dynamics to determi...
Circularly Polarized Luminescence Optical Waveguides Based on One-Dimensional Hybrid Copper-Silver Bromide Crystal [0.03%]
基于一维铜银溴化物杂化晶体的圆偏振光波导
Yuxuan Wang,Yi Wei,Xiaofan Xu et al.
Yuxuan Wang et al.
Chiroptical waveguides, capable of generating and propagating circularly polarized light (CPL), hold significant promise for next-generation optoelectronic devices. However, developing novel, efficient chiroptical waveguides remains challen...
Transition-Metal-Free Carbonyl Redox: A Ketene in Three Oxidation States [0.03%]
无过渡金属卡宾氧化还原化学：三种氧化态的亚乙烯基物种
Liankun Ai,Xinyue Meng,Songyang Li et al.
Liankun Ai et al.
Ketenes are among the most versatile compounds in organic chemistry, participating in a wide range of transformations, including cycloadditions, nucleophilic and electrophilic additions, and polymerizations. However, their redox chemistry, ...
Synthesis of Hydroxy-Functionalized Polyethylene via Radical Copolymerization of Ethylene with Alkenyl Boronate and Post-Polymerization Oxidation [0.03%]
通过自由基共聚和后续聚合氧化合成羟基官能化聚乙烯
Tomoaki Kanazawa,Tommaso Posenato,Sébastien Norsic et al.
Tomoaki Kanazawa et al.
Radical copolymerization of ethylene was performed with alkenyl boronate, and post-polymerization oxidation was conducted to synthesize hydroxy-functionalized polyethylene (PE). The copolymerization behavior was dependent on the molecular s...
Sterically Congested LLX-Type PNSi Tridentate Ligands for Iridium-Catalyzed C(sp3)-H Borylation [0.03%]
拥挤的LLX型PNSi三齿配体用于铱催化C(sp3)–H硼化反应
Takeru Torigoe,Akika Kon,Kairi Mine et al.
Takeru Torigoe et al.
Iridium catalysts bearing LLX-type PNSi tridentate ligands (Ir/PNSi catalysts) were developed as new effective catalysts for the C(sp3)-H borylation of alkanes and alkyl groups that do not have directing groups. The Ir/PNSi catalysts were p...
Xikun Zhang,Hongtao Qu,Weibin Yan et al.
Xikun Zhang et al.
Sodium-based dual-ion batteries (SDIBs) have garnered increasing attention as a next-generation energy storage technology, owing to their high operating voltage, cost-effective raw materials, and environmentally friendly characteristics. Th...
Difluoro Carbenes: From Genuine Gold Complexes to Unprecedented Metallacyclic Reactivity [0.03%]
二氟卡宾：从经典的金配合物到前所未有的金属环状反应性
David Vesseur,Shuo Li,Nina Albouy et al.
David Vesseur et al.
Difluorocarbene is a very powerful synthon in organic chemistry, but its reactivity is very challenging to tame. While a few recent studies have pinpointed the potential of transition metals such as Pd and Cu to stabilize and harness difluo...
Jess M. Clough [0.03%]
杰斯·M·克洛夫
Jess M Clough
Jess M Clough
"If I were a piece of lab equipment, I would be a TLC plate because I enjoy breaking down complicated problems into their individual components… The most important future application of my research is the design of polymeric materials that...
Bifunctional Silylene-Aminoborane Enables Cooperative Activation of Unsaturated Bonds and Access to Heteroatom-Enriched Polycycle [0.03%]
双功能硅YLE-氨基硼烷促进不饱和键的协同活化及杂原子富集多环产物的获得
Zheng Su,Mingdong Zhong,Xixi Meng et al.
Zheng Su et al.
We report the synthesis and cooperative reactivity of a bifunctional silylene-aminoborane compound, 1-Ph-2-tBu-1H-2,1-benzazaborolyl-(amidinato)silylene (1), designed to preserve the ambiphilicity of both functional units while preventing i...