Coordination-Driven Direct C─H Metalation of N-Heterocycles With a Superbasic Co(II) Amide Co(TMP)2 [0.03%]
超碱性钴胺idesCo(TMP)₂促进的N杂环直接C−H金属化反应
Na Jin,Manting Mu,Max García-Melchor et al.
Na Jin et al.
Metalation of N-heterocycles such as pyridines or diazines with conventional alkali metal bases is particularly challenging due to the limited activation of their C─H bonds coupled with the thermal fragility of the resulting organometallic...
Rufeng Fan,Jiahui Ni,Tiantian Zhou et al.
Rufeng Fan et al.
In recent years, proximity-inducing drugs have emerged as a novel therapeutic modality that induces or stabilizes protein-protein interactions, especially by recruiting effector proteins to specific target proteins, thereby achieving functi...
Electron-Induced C─F Bond Activation in Sn6-oxo Cluster Resist for Enhanced Sensitivity and Sub-10-nm Patterning [0.03%]
用于增强感光度和亚10nm图形化的含氧锡六聚簇抗反射材料中的C-F键活化研究
Wenzheng Li,Min Zhang,Yingdong Zhao et al.
Wenzheng Li et al.
Metal-oxo cluster (MOC) resists are promising candidates for extreme ultraviolet lithography (EUVL), but optimizing the resolution, line-edge roughness (LER), and sensitivity (RLS) trade-off remains challenging. Leveraging dissociative elec...
Diastereodivergent Hydroamidation of Methylenecyclohexanes With Differentiated Active Catalytic Species [0.03%]
具有不同活性催化物种的蒈烷二烯和降蒈烷二烯的非对映选择性氢氨化反应
Zhen Li,Yi-Zhou Tong,Kai-Ran Duan et al.
Zhen Li et al.
The construction of three-dimensional (3D) organic molecular structures is pivotal in modern organic chemistry. For three dimensionally structured disubstituted cyclohexanes, which exist as two possible configurations (cis- and trans-), sub...
Phosphoryl-Engineered MOFs Promote Interfacial Reconstruction for Efficient Seawater Ethanol Electrooxidation [0.03%]
磷改性MOF促进界面重构用于高效的海水乙醇电氧化反应
Jieting Ding,Tingyu Liu,Liu Zhu et al.
Jieting Ding et al.
The hydrogen production efficiency of hybrid seawater electrolysis devices hinges on high-performance catalytic materials with superior activity and chlorine corrosion resistance under the alkaline seawater conditions. However, the controll...
Synergistic Interaction Between N-Heterocyclic Carbene (NHC)-Anchored Cu(I) Atom and In Situ-Generated Cu Nanoparticles in a Post-Modified MOF-808 Framework Promoting C─C Coupling in CO2 Reduction [0.03%]
氮杂环卡宾(NHC)锚定的Cu(I)原子和原位生成的Cu纳米粒子在后修饰MOF-808框架中的协同作用促进CO2还原过程中的C-C耦合反应
Li-Hong Jia,Xian-Ming Zhang
Li-Hong Jia
The electrochemical reduction of CO2 to high-value chemicals like C2H4 represents a promising route for sustainable energy and CO2 mitigation. However, its efficiency remains constrained by the high energy barrier for C─C bond formation an...
Perylene Diimide-Derived Bis(Macrocyclic) Ligand Affords Chiral Multinuclear Pd(II) Complexes via Direct Bay-Region Palladation [0.03%]
基于苯并菲二酰亚胺的双大环配体通过拜尔区域直接钯化得到手性多核Pd(II)配合物
He-Ye Zhou,Shasha Yan,Huaxi He et al.
He-Ye Zhou et al.
Macrocyclic ligands provide powerful access to structurally defined multi-metallic architectures, yet direct π-core metalation of imide-functionalized polycyclic aromatic dyes remains difficult to control. Herein, we present the design and...
3D-Printable Nanoporous Thermosets via Disulfide-Based Polymerization-Induced Microphase Separation [0.03%]
基于二硫化物的聚合物微相分离制备可用于3D打印的纳米多孔热固性树脂
Xueheng Dai,Kenny Lee,Yuan Xiu et al.
Xueheng Dai et al.
Interconnected nanoporous polymer networks are central to applications that demand rapid mass transport, yet their fabrication by polymerization-induced microphase separation (PIMS) remains constrained by fixed macroCTA polarity, limited fo...
Unlocking an All-Anisotropic-Component Integrated Paradigm Toward Practical Solid-State Zinc Metal Pouch Cells [0.03%]
面向实际固态锌金属袋式电池的全各向异性组件集成范式的解锁
Dingtao Ma,Xiaodan Yang,Ming Yang et al.
Dingtao Ma et al.
High-safety and low-cost Zn metal batteries hold great promise for energy storage, but their limited energy density remains a major bottleneck restricting their practical development. Here, an all-anisotropic-component integrated model with...
Fibroblast-Mimetic Lignin Polymersomes for Logic-Gated Synthesis of Mechanically Reconfigurable Bioskins [0.03%]
仿成纤维细胞木质素聚合物囊泡的逻辑门控制合成可机械重构的生物皮肤
Hairong Wang,Xujing Liu,Zijun Mao et al.
Hairong Wang et al.
Ageing is inevitable and accompanied by progressive loss of skin elasticity. Fibroblasts, embedded within the extracellular matrix, finely regulate skin mechanics via membrane-bound ligands. Creating synthetic assemblies that mimic fibrobla...