Coordination-Driven Direct C─H Metalation of N-Heterocycles With a Superbasic Co(II) Amide Co(TMP)2
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Metalation of N-heterocycles such as pyridines or diazines with conventional alkali metal bases is particularly challenging due to the limited activation of their C─H bonds coupled with the thermal fragility of the resulting organometallic intermediates. Buil... ...