Ligand-Isomerization Strategy Achieves Exceptional Wide-Range Zero-Thermal-Quenching Phosphorescence in Copper-Iodide Cluster-Organic Frameworks [0.03%]
配体异构化策略实现铜碘簇有机框架材料的宽范围零温淬灭磷光
Hao Sun,Yang Chen,Yuye Sun et al.
Hao Sun et al.
Copper(I)-halide cluster materials have attracted considerable research interest for advanced optoelectronic applications, owing to their exceptional photophysical characteristics. Nevertheless, their luminescent performance is significantl...
Engineering Li2ZrCl6 with Ga3+/Ge4+ Doping for High Ionic Conductivity and Stable Interfaces in Solid-State Batteries [0.03%]
用于固态电池的高离子电导率和稳定界面的Li2ZrCl6(Ga3 +/ Ge4 +掺杂)工程化研究
Yao Wu,Yushu Liu,Xiao Huang et al.
Yao Wu et al.
The solid electrolyte Li2ZrCl6 has attracted significant attention due to its low cost and good compatibility with high-voltage cathode materials. Although it exhibits considerable ionic conductivity at room temperature, it still falls shor...
Self-Healing Antibacterial Metallosupramolecular Soft-Networks: Comparative Studies on Mechanical Flexibility and Semiconducting Device Applications [0.03%]
自修复抗菌金属超分子软网络：力学柔韧性和半导体器件应用的比较研究
Biswajit Dey,Indrajit Pal,Kunal Kumar Saha et al.
Biswajit Dey et al.
Mn(II)/Ni(II)-salts and 2,5-pyridinedicarboxylic acid (PDA)-based individual supramolecular metallogels (i.e., Mn-PDA and Ni-PDA) are achieved by maintaining specific stoichiometric ratios of distinct metal salts and PDA (i.e., 1:1). 2,5-Py...
The Metal Coordination Effects on the Optoelectronic Properties of Perylene Diimide and Nucleotide Supramolecular Complex (GMP:PDI: Ag(I)/Co(II)/Zn(II)): Computational and Experimental Studies [0.03%]
金属配位对嘌呤核苷酸与苝二酰亚胺超分子配合物(GMP:PDI:Ag(I)/Co(II)/Zn(II))光电子性质的影响：计算与实验研究
Ali Raza Ayub,Salba,Muhammad Zeshan et al.
Ali Raza Ayub et al.
In this comprehensive investigation, we present an integrated computational and experimental study of a series of metal-doped supramolecular PDI(β-ala)-GMP complexes using Ag(I)/Co(II)/Zn(II) as central metal ions. The supramolecular assem...
N-Formylation of Amines by a Magnetically Separable Cobalt Nanocatalyst Using CO2 as a C1 Source [0.03%]
磁性分离钴纳米催化剂以CO2为C1源胺的N-甲酰化反应
Rimpa Mondal,Sumanta Mondal,Rinku Ghanta et al.
Rimpa Mondal et al.
Utilizing CO2 for the synthesis of value-added chemicals offers an economically viable route while contributing to reducing greenhouse gas emissions. In this study, three ligands with N2O2 binding sites were designed and used to synthesize ...
Direct Arylation of Unactivated Arenes Using Earth-Abundant Iron/Tetra-Aza Macrocyclic Complexes [0.03%]
使用富集铁/四氮杂大环络合物直接偶联非活化芳烃
Tahmina Afroz,David M Freire,Timothy J Hubin et al.
Tahmina Afroz et al.
Biaryl motifs are central in pharmaceutical drug design, yet conventional synthesis via palladium-catalyzed cross-coupling poses increasing sustainability and cost concerns. The study presented herein explores a greener alternative to palla...
Catalytic Isotope Effects of 107Ag/109Ag in the Photocatalytic Degradation of Methyl Orange [0.03%]
107Ag/109Ag同位素效应的光催化降解甲基橙研究
Yu-Bing Xue,Jing Zhao,Tiantian Jin et al.
Yu-Bing Xue et al.
Nuclear structure and properties are mainly studied by utilizing large-scale equipment such as colliders, while the chemical behavior of isotopes and their isotopologues emerges as a critical approach to investigating nuclei. Studies of iso...
An Acid-Resistant Hf6-MOF for the Luminescence Sensing of Biomarkers with High Sensitivity and Selectivity [0.03%]
一种用于生物标志物高灵敏度和选择性发光检测的耐酸Hf6-MOF
Jie Dong,Man Yu,Xiang Xiong et al.
Jie Dong et al.
Although the detection of biomarkers epinephrine (EP) and homovanillic acid (HO) is critical for early diagnosis and personalized medicine, the development of a luminescent sensor for their precise quantification remains an ongoing challeng...
Tuning Au → M Interactions: d-Block Metalloligands Enhance Au-Catalyzed CO2 Hydrosilylation [0.03%]
调节Au→M相互作用：d区金属亚胺卡宾配体促进Au催化的CO2硅氢化反应
M Alexander Eltester,Claudia D Roth,Michael E Tauchert
M Alexander Eltester
L2Z-type ligands are powerful platforms for fine-tuning π-acidic AuI catalysis. In this paper, we present a series of [(L2Z)AuICl]n+ and [(L2Z)AuI](n+1)+ complexes in which Mn2+, Fe2+, Co2+, Zn2+, Cu+, Ag+, Cd2+, and Tl+ act as Z-type meta...
AIE-Active Tetrazolyl Tetraphenylethylene-Based Metal-Organic Framework as Highly Selective Chemosensor for Nitro Explosives [0.03%]
一种用于硝基炸药高选择性化学传感器的具有AIE活性的四苯乙烯基四氮唑金属有机骨架化合物
Senyu Zhang,Haoyu Chen,Chenxi Xu et al.
Senyu Zhang et al.
The development of fast and sensitive fluorescence sensors for nitro-explosive detection in aqueous environments remains a critical challenge for security and environmental monitoring. This work presents two novel metal-organic frameworks (...