Tuning Au → M Interactions: d-Block Metalloligands Enhance Au-Catalyzed CO2 Hydrosilylation
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L2Z-type ligands are powerful platforms for fine-tuning π-acidic AuI catalysis. In this paper, we present a series of [(L2Z)AuICl]n+ and [(L2Z)AuI](n+1)+ complexes in which Mn2+, Fe2+, Co2+, Zn2+, Cu+, Ag+, Cd2+, and Tl+ act as Z-type metalloligands. The resu... ...
