Molybdenum(VI) borano-imido complexes and their application as Lewis acid catalysts in homocoupling of diazo compounds [0.03%]
钼(Ⅵ)亚胺硼配合物及其作为路易斯酸催化剂应用于偶氮化合物的同耦合反应中
Karel Škoch,Michaela Buziková,Michał Jakubczyk et al.
Karel Škoch et al.
We report the synthesis, structural characterization, and catalytic activity of a borano-imido molybdenum complex featuring a unique motif B-NMoCl4(thf), prepared via the reaction of a phenylpyridine-based boron azide with [MoCl4(thf)2]. ...
Eu3+ doped Y3+ dipicolinate crystals: differences in the luminescence spectra and concentration quenching of Eu3+ luminescence [0.03%]
掺入Y^3+二吡啶酸盐晶体中的Eu^3+发光光谱差异及Eu^3+发光浓度猝灭效应
Sabina Svava Mortensen,Thomas Just Sørensen
Sabina Svava Mortensen
Materials doped with lanthanide(III) ions are used in solar cells, LEDs, bioimaging etc. However, we still need to understand the effect of concentration on the luminescence properties. Here, the Na(Gua)2[Ln(DPA)3]·6H2O crystal system is e...
Matthew de Vere-Tucker,Imogen Squire,Michelangelo Tritto et al.
Matthew de Vere-Tucker et al.
Amidinates ([R1NC(R2)NR3]-) are versatile and ubiquitous ligands in inorganic and main group chemistry, due to their anionic, bidentate nature and easy tunability. Herein we present the synthesis of 23 bulky N-aryl substituted aminidinate l...
Homoleptic complexes of vanadium and N-heterocycles made via oxidation of vanadium nanoparticles [0.03%]
通过氧化钒纳米粒子制备的含vanadium和N杂环的齐藤化合物
Lena Baumgärtner,Claus Feldmann
Lena Baumgärtner
The four homoleptic coordination compounds [NaV(cbz)4] (1), [V(bipy)3] (2), [V(phen)3] (3), and [V(Hai)3(ai)2]·0.5 tol (4) are prepared by the reaction of vanadium metal (V(0)) nanoparticles (mean size: 1.6 ± 0.3 nm) with the sterically d...
Surface engineering of SRMIST-2 using amine-functionalized polyhedral oligomeric silsesquioxane for tunable wettability and sustainable oil-water separation [0.03%]
基于氨基功能化的多面低聚倍半硅氧烷的SRMIST-2表面改性研究：实现可调湿性和长效油水分离性能
Sankar Sathish,Arunkumar Chinnusamy,Kesavan Muthu et al.
Sankar Sathish et al.
Oil spills and industrial pollutants present a severe and persistent threat to aquatic ecosystems and global environmental health. These contaminants not only degrade water quality but also initiate a cascade of environmental issues that ca...
Ligand-field symmetry and magneto-optical correlations in a luminescent Dy(III) single-molecule magnet [0.03%]
发光Dy(III)单分子磁体的配体场对称性和磁光相关性
Senthil Kumar Kuppusamy,Christian Pachl,Zhaoyang Jing et al.
Senthil Kumar Kuppusamy et al.
The establishment of ligand field (LF) symmetry around lanthanoid (Ln(III)) centres is of paramount importance to understand factors that govern magnetization relaxation in single-molecule magnets (SMMs). We investigated a luminescent monon...
Crystal structure and physical properties of shchurovskyite-related K2CaCu6O2(PO4)4 [0.03%]
与什楚罗夫斯基石相关的K2CaCu6O2(PO4)4晶体结构和物理性质
G V Kiriukhina,O V Yakubovich,L V Shvanskaya et al.
G V Kiriukhina et al.
A new oxocuprate phosphate, K2CaCu6O2(PO4)4, was obtained as tabular dark-green single crystals through flux-assisted high-temperature synthesis. It crystallizes in the space group P2/c and represents the centrosymmetric modification of the...
Competing but coexisting: sulfate- and potassium-induced supramolecular motifs in squaramide-based receptor complexes [0.03%]
竞争但共存：硫酸盐和钾离子诱导的基于双氮杂色满酰胺受体的超分子基元
Damian Jagleniec,Marcin Wilczek,Łukasz Dobrzycki et al.
Damian Jagleniec et al.
We explore the coexistence and interplay of two distinct supramolecular motifs within a single receptor molecule combining squaramide and benzo-15-crown-5 ether domains. These heteroditopic systems display a dual recognition behavior, formi...
Amorphous vanadium-doped iron borate/tetraboride hybrid as an efficient electrocatalyst for the oxygen evolution reaction [0.03%]
非晶钒掺杂铁硼酸盐/四硼化物合金电催化剂用于析氧反应
Tanbir Ahmed,Santanu Pal,Nibedita Sinha et al.
Tanbir Ahmed et al.
The design of an effective electrocatalyst as a replacement for a conventional expensive electrocatalyst for facilitating the sluggish oxygen evolution reaction (OER) at the anode has been identified as an effective way to make hydrogen pro...
NO photoswitches: a single photoinduced linkage isomer in diamagnetic {MNO}8 complexes [0.03%]
无光切换型分子开关：磁性八核{MNO}8化合物中的单构象光异构体物种
Artem A Mikhailov,Axel Gansmüller,Asma Hasil et al.
Artem A Mikhailov et al.
Representative for the {MNO}8 series of metal-nitrosyl compounds, the neutral {CoNO}8 cobalt nitrosyl complex [Co(fpin)NO(phen)] (1) with fpin = perfluoropinacolate(2-) and phen = phenanthroline(0) exhibits a single photoinduced linkage iso...