Homoleptic complexes of vanadium and N-heterocycles made via oxidation of vanadium nanoparticles
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The four homoleptic coordination compounds [NaV(cbz)4] (1), [V(bipy)3] (2), [V(phen)3] (3), and [V(Hai)3(ai)2]·0.5 tol (4) are prepared by the reaction of vanadium metal (V(0)) nanoparticles (mean size: 1.6 ± 0.3 nm) with the sterically demanding N-H-acidic/... ...
