Tailoring LiPF6-based electrolyte solvation structures via solvent regulation strategies for low-temperature lithium metal batteries [0.03%]
Huiying Wang,Jiawei Zhang,Xi Wang et al.
Huiying Wang et al.
Lithium metal batteries (LMBs) offer exceptional energy density, yet their practical application is limited by unstable solid electrolyte interphase (SEI) formation and sluggish Li+ transport, particularly under low-temperature conditions. ...
Cubane lanthanoid complexes with tridentate [O, PO, O] coordination using tris(5- tert-butyl-2-hydroxyphenyl)-phosphine oxide ligands: synthesis, characterisation, and magnetic behaviour [0.03%]
Patrick Mangundu,Curtis C Ho,Richard A Mole et al.
Patrick Mangundu et al.
Functionalised ortho-aryl phosphine oxides are assessed as candidates for lanthanoid (Ln) coordination. The series of tetranuclear Ln complexes synthesised [{Ho(μ3-OH)(μ2,κ3-LH)(C2H5OH)}4] (1), [{Dy(μ3-OH)(μ2,κ3-LH)(C2H5OH)}3{Dy(μ3-O...
Enhancing the ORR activity of Fe-based perovskite cathodes for intermediate-temperature solid oxide fuel cells: alternative strategies and performance optimization [0.03%]
Long Li,Qi Qian,Zihan Ma et al.
Long Li et al.
Solid oxide fuel cells (SOFCs) have attracted much attention due to their high efficiency and environmental friendliness. However, high operating temperatures lead to material degradation, which limits their application. When the temperatur...
Double second-order Jahn-Teller strategy driven NLO response in sulfate crystal Nb2O2(TeO3)2(SO4) with a large birefringence [0.03%]
Jingsha Xu,Xiaofeng Zhang,Shanshan Chen et al.
Jingsha Xu et al.
Nonlinear optical (NLO) crystals serve as indispensable components in laser technology. Many modifications of sulfate-based NLO materials rely on introducing a single type of functional cation, which in some cases leads to an imbalanced imp...
Spontaneous assemblies of gigantic polyoxomolybdates; from structure and properties to synthetic methods [0.03%]
Vishal Lakhanpal,De-Liang Long,Leroy Cronin
Vishal Lakhanpal
Gigantic polyoxomolybdates, dominated by the Molybdenum Blue (MB) family, constitute a key subclass of polyoxometalates (POMs) and play a fundamental role in elucidating structural construction principles and showcasing the diversity of POM...
Synthesis of hybrid phosphinoferrocene ligands bearing amine pendants and catalytic evaluation of their gold(I) complexes [0.03%]
David Rezazgui,Ivana Císařová,Petr Štěpnička et al.
David Rezazgui et al.
A series of hybrid, ferrocene-based phosphines bearing additional amine substituents have been synthesized and evaluated in gold catalysis. The series includes 1,1'- and 1,2-disubstituted phosphinoferrocene donors with cyclic or acyclic ami...
Janus-faced coordination chemistry of pyridyl-functionalized phosphinines with Cu(I) and Au(I) [0.03%]
Richard O Kopp,Nathan T Coles,Moritz J Ernst et al.
Richard O Kopp et al.
The novel 2,6-trimethylsilyl-3,5-(2'-pyridyl)phosphinine has been synthesized and its coordination chemistry with Cu(I) and Au(I) was investigated. Selective binding through either the phosphorus atom or the pendant pyridyl groups was achie...
Centrosymmetric to noncentrosymmetric structure transition of the RbREP2Se6 (RE = La-Nd, Sm, Ho-Yb) series: crystal growth, magnetic and optical properties [0.03%]
Habiba Binte Kashem,Md Abdullah Al Muhit,Hope Eden Smith et al.
Habiba Binte Kashem et al.
Rare-earth (RE) chalcophosphates have attracted considerable attention as infrared nonlinear optical (NLO) materials. Herein, nine single crystals of quaternary rare-earth containing selenophosphates, RbREP2Se6 (RE = La-Nd, Sm, Ho-Yb) were ...
Uncovering lithium iron metaphosphate as a cathode material through organophosphate-assisted one-pot synthesis [0.03%]
Yongda Guo,Jingbo Huang,Junzhen Wei et al.
Yongda Guo et al.
Metaphosphate-based polyanionic compounds represent an underexplored class of cathode materials for lithium-ion batteries, despite their rigid framework chemistry and intrinsic safety advantages. Herein, we report the first systematic inves...
Reactivity of homodinuclear rare-earth metal complexes with an indol-2-yl-based pincer ligand toward nitrogen- and oxygen-containing compounds [0.03%]
Jianwu Wen,Fuxiang Chai,Yonghu Bao et al.
Jianwu Wen et al.
Diverse reactivity of homodinuclear rare-earth metal alkyl complexes (rare-earth metals = Gd, Dy, Y, Er, Yb, and Lu) supported by an indol-2-yl-based pincer ligand with nitrogen- and oxygen-containing organic compounds has been explored, re...