Cubane lanthanoid complexes with tridentate [O, PO, O] coordination using tris(5- tert-butyl-2-hydroxyphenyl)-phosphine oxide ligands: synthesis, characterisation, and magnetic behaviour
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Functionalised ortho-aryl phosphine oxides are assessed as candidates for lanthanoid (Ln) coordination. The series of tetranuclear Ln complexes synthesised [{Ho(μ3-OH)(μ2,κ3-LH)(C2H5OH)}4] (1), [{Dy(μ3-OH)(μ2,κ3-LH)(C2H5OH)}3{Dy(μ3-OH)(μ2,κ3-LH)(H2O)}... ...
