Sterically crowded phenanthrolinediamides: conformational behavior and photophysics of their complexes with an Eu-Gd-Tb triad [0.03%]
拥挤的菲并苯二酰胺：与Eu-Gd-Tb三元系形成的配合物的构象行为和光物理性质研究
Nane A Avagyan,Roman V Zonov,Pavel S Lemport et al.
Nane A Avagyan et al.
Three positional isomers of alkyl-aryl-substituted 1,10-phenanthroline-2,9-dicarboxamides (DAPhens) were synthesized and investigated. Using quantum chemical modeling, the difference in the conformational behavior of new DAPhens and their c...
Dinuclear copper(I) halide complexes containing unsymmetric diphosphine: structure, photophysical and photocatalytic hydrogen production properties [0.03%]
含不对称二磷配体的二核铜(I)卤化物配合物的结构、光物理和光催化制氢性质
Shi-Ji Li,Li Liu,Xin-Xin Zhong et al.
Shi-Ji Li et al.
Highly emissive Cu(I) halide complexes with short decay lifetimes (several μs scale) have attracted attention. Here, three dinuclear four-coordinate Cu(I) halide complexes containing unsymmetric diphosphine [Cu2X2(L1)2] (L1 = 9-(4,5-bis(di...
Automated bond valence sum analysis for crystallographic database quality assessment: a systematic study of rock salt oxides, halides, and chalcogenides [0.03%]
用于岩盐氧化物、卤化物和硫属化合物晶体学数据库质量评估的自动化键价和分析：系统研究
Nik Reeves-McLaren
Nik Reeves-McLaren
Crystallographic databases are vital for research and increasingly serve as training data for machine learning in materials discovery, yet systematic quality assessment at database scale remains absent. Bond valence sum (BVS) analysis - tes...
A perspective on the applications of Schiff base metal complexes in photovoltaic and light emitting devices: the tunability and effect of structural modifications [0.03%]
Schiff碱金属配合物在光伏和发光器件中的应用展望——结构改性调控及影响效应探讨
Nilotpal Goswami,Soumya Bhattacharjee,Pranjit Barman
Nilotpal Goswami
Schiff base metal complexes have been widely explored due to their high utilities in a diverse range of areas, including therapeutics, optical/electrochemical sensors, and environmental remediation. Their unique photophysical and electroche...
Two-dimensional metal-organic framework/graphene oxide composites as proton conductors: chemical grafting vs. physical blending [0.03%]
二维金属有机骨架/石墨烯氧化物复合材料作为质子导体的研究：化学接枝与物理共混的区别
Chi-Lun Chuang,Chou-Hung Hsueh,Kuan-Chu Wu et al.
Chi-Lun Chuang et al.
A water-stable two-dimensional (2D) zirconium-based metal-organic framework (MOF), ZrBTB (BTB = 1,3,5-tri(4-carboxyphenyl)benzene), serves as a porous platform to integrate with graphene oxide (GO) in order to achieve ultrahigh proton condu...
An iron(IV)-oxo intermediate on a carbanionic ligand framework: reactivity and decay pathways [0.03%]
铁(IV)-超氧配合阴离子的反应性及其分解途径
Arghyadip Bhowmik,Shreetama Bhattacharya,Sridhar Banerjee et al.
Arghyadip Bhowmik et al.
An iron(II) complex, [(L1)FeII(CH3CN)2]+ (1), (L1 = tris(2-pyridylthio)methanido) of the monoanionic N3C donor ligand, upon treatment with isopropyl 2-iodosylbenzoate, generates the iron(IV)-oxo intermediate, [(L1)FeIV(O)(CH3CN)]+ (2). The ...
Isomers of 2,2':6',2″-terpyridine and 2,6-dipyrazin-2-ylpyridine with aliphatic substituents: synthesis, coordination chemistry, and catalytic and anticancer activities [0.03%]
具有脂肪族取代基的2,2':6',2″-三(吡啶-2-基)苯和2,6-双(吡嗪-2-基)吡啶异构体：合成，配位化学及其催化性能与抗癌活性研究
Guoqi Zhang,Haiyu Mei,Amy Kanina et al.
Guoqi Zhang et al.
While the synthesis of 4'-aryl substituted 2,2':6',2″-terpyridine and its common isomer 4,2':6',4″-terpyridine is trivial using the one-pot Krönke condensation procedure, their 4'-alkyl substituted ligands have been sparsely approached. ...
Chirality-controlled biomolecular recognition in Cu(I) metallodrugs: the first enantiomorphic CuP2O2 systems with dual DNA/LOX activity [0.03%]
手性控制的生物分子识别在Cu(I)金属药物中：第一个具有对映体DNA / LOX活性的CuP2O2系统
S K Hadjikakou,T M Koufou,C N Banti et al.
S K Hadjikakou et al.
Copper(II) nitrate reacts with tris(m-tolyl)phosphine (m-MePh)3P in 1 : 2 and 1 : 3 molar ratios to form [Cu((m-MePh)3P)2(NO3)] (1) which contains two isomers (1A and 1B) in the crystal lattice and [Cu((m-MePh)3P)3(NO3)] (2). The reaction o...
Ni3S2@Ni3Se2 electrocatalysts for enhanced hydrogen and oxygen evolution reactions [0.03%]
用于改善氢气和氧气演化的Ni3S2@Ni3Se2电催化剂
Xinrui Bai,Xinlan Guo,Xiang Wu
Xinrui Bai
Developing cost-effective and robust non-noble metal bifunctional electrocatalysts is critical for sustainable hydrogen production via electrochemical water splitting. However, the practical application is often restricted by the sluggish k...
Room-temperature and one-minute synthesis of alcohol-soluble and ultra-small Eu-doped CaMoO4 nanoparticles [0.03%]
室温下一分钟内合成醇溶性和超小的Eu掺杂CaMoO4纳米颗粒
Ling Zhong,Mengxin Liu,Xin Su et al.
Ling Zhong et al.
Lanthanide (Ln3+) doped alkaline earth metal molybdates (AMoO4, A = Ca, Sr, Mg) have been widely investigated owing to their excellent photoluminescence properties. Alcohol-soluble and ultra-small Eu3+-doped CaMoO4 nanocrystals are prepared...