An iron(IV)-oxo intermediate on a carbanionic ligand framework: reactivity and decay pathways
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An iron(II) complex, [(L1)FeII(CH3CN)2]+ (1), (L1 = tris(2-pyridylthio)methanido) of the monoanionic N3C donor ligand, upon treatment with isopropyl 2-iodosylbenzoate, generates the iron(IV)-oxo intermediate, [(L1)FeIV(O)(CH3CN)]+ (2). The strong ligand field ... ...
