[Ru6(μ6-Sb)(CO)18]3-: deeply reduced metal carbonyl cluster embedded with naked μ6-Sb [0.03%]
[Ru6(μ6-Sb)(CO)18]3-：夹杂有裸露的μ6-Sb的高配位金属碳基簇离子
Cheng Ding,Xian Xu,Qian Qin et al.
Cheng Ding et al.
The redox reaction of K3Sb and Ru3(CO)12 in the ethylenediamine (en) of 2,2,2-cryptand produces the deeply reduced [Ru6(μ6-Sb)(μ2-CO)2(CO)16]3- (1), wherein the unprecedented boat-like Ru6 cluster unit is embedded with μ6-Sb for the firs...
Correction: Enhanced photocatalytic activity of g-C3N4/MnO composites for hydrogen evolution under visible light [0.03%]
纠正：g-C3N4/MnO复合物在可见光下用于析氢的光催化活性增强
Na Mao,Xiaomin Gao,Chong Zhang et al.
Na Mao et al.
Correction for 'Enhanced photocatalytic activity of g-C3N4/MnO composites for hydrogen evolution under visible light' by Na Mao, et al., Dalton Trans., 2019, 48, 14864-14872, https://doi.org/10.1039/c9dt02748c.
Published Erratum
Dalton transactions (Cambridge, England : 2003). 2026 Feb 17. DOI:10.1039/d6dt90017h 2026
Analysis of the charge/discharge mechanism of an Fe-containing Li2S positive electrode material and its visualization by computational simulation [0.03%]
基于计算模拟的含铁Li2S正极材料充放电机理分析及可视化研究
Tomonari Takeuchi,Yoyo Hinuma,Koji Ohara et al.
Tomonari Takeuchi et al.
The structure and charge/discharge mechanism of an Fe-containing Li2S-based positive electrode material (Li8FeS5) were investigated using X-ray scattering and absorption spectroscopy analyses. Conventional XRD measurements indicated that Li...
Monocoordinated nitrenes and heavier pnictinidenes: transient to bottleable compounds [0.03%]
单配位亚胺类和更重的氮元素同类物：瞬态到瓶装化合物
Sandeep Kumar,Kanishk Tomer,Avnish Singh et al.
Sandeep Kumar et al.
Nitrenes (N-R) and heavier pnictinidenes (Pn-R; Pn = P-Bi, R = anionic substituents), which are monovalent group 15 elements, have long been regarded as fleeting reactive intermediates in organic chemistry, with their existence typically co...
Tuning the morphology of ZnCdS@CeO2 Z-scheme heterostructures from core-shell to core-satellite for superior photocatalytic performance [0.03%]
ZnCdS@CeO2 Z-型异质结形貌调控（从核壳到“核卫星”结构）增强光催化性能
Yong Liu,Baowei Shen,Sijia Zhao et al.
Yong Liu et al.
In addition to solar cells, photocatalysis is an alternative way for the direct utilization of clean and sustainable solar energy. Currently, the core challenge in photocatalysis is the efficiency of the separation and transfer of the photo...
Synthesis of octacalcium phosphate with incorporated 1,4,5,8-naphthalenetetracarboxylate ions [0.03%]
掺入1,4,5,8-萘四甲酸根离子的八钙磷酸盐的合成
Taishi Yokoi,Mio Yoshizaki,Masaya Shimabukuro et al.
Taishi Yokoi et al.
This study reports the successful synthesis of octacalcium phosphate (OCP) with incorporated 1,4,5,8-naphthalenetetracarboxylate ions. This material achieves a new record for the maximum molecular weight of carboxylic acids that can be inco...
Sulfur insertion into group 12 metal dithiolate complexes: metal-dependent equilibria [0.03%]
第12族金属二硫醇配合物中的硫插入反应：金属依赖平衡效应
Muhammad Sohail,Carsten Heinsen,Allen G Oliver et al.
Muhammad Sohail et al.
Dianionic bis(carboxamide)pyridine-supported metal(II) dithiolate complexes of Cd2+ and Hg2+ showed isostructural [N3S2] coordination to a previously reported zinc variant, but changes in ionic radius resulted in distortion of the coordinat...
Crystallographic insights into (ImHR)2[TcBr6] (Im = imidazole, R = H, Me, Et): non-covalent interactions and mass spectrometry [0.03%]
咪唑合六溴化 techn(III) 的晶体学研究：非共价相互作用及质谱分析
Anton P Novikov,Mikhail A Volkov,Mikhail S Grigoriev
Anton P Novikov
The structures of three Tc(IV) complexes (ImHR)2[TcBr6] (Im = imidazol-2-yl, R = H, Me, Et) are described. The compound (ImHMe)2[TcBr6] was obtained in two distinct polymorphic forms (space groups P1̄ and P21212), arising from differences ...
Unveiling field-induced single-ion magnetism in pentacoordinate and heptacoordinate cobalt(II), dysprosium(III) and terbium(III) complexes with a tridentate bis(benzimidazole)pyridine ligand [0.03%]
一种三齿含氮酰咪唑配体五/七配位单离子磁性钴(II)、镝(III)和铽(III)配合物的合成及表征
Nikoleta Malinová,Ján Pavlik,Kamil Kotrle et al.
Nikoleta Malinová et al.
We report the synthesis, crystal structures, and magnetic properties of three Co(II) and two Ln(III) (Dy, Tb) complexes, all containing the tridentate ligand 2,6-bis(3-methoxypropyl-1H-benzimidazol-2-yl)pyridine (L). The pentacoordinate Co(...
Beyond bond distances: a purely geometrical descriptor correlating with covalency-related bonding terms [0.03%]
超越键长：一个与共价性相关的纯几何学描述符
Jorge Pardos,Jorge Gonzalo,Pedro Merino et al.
Jorge Pardos et al.
Quantifying covalency remains a central challenge in understanding chemical bonding. Traditional distance-bond strength correlations often fail in diverse bonding regimes, and most existing metrics require computationally demanding electron...