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Crystallographic insights into (ImHR)2[TcBr6] (Im = imidazole, R = H, Me, Et): non-covalent interactions and mass spectrometry

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The structures of three Tc(IV) complexes (ImHR)2[TcBr6] (Im = imidazol-2-yl, R = H, Me, Et) are described. The compound (ImHMe)2[TcBr6] was obtained in two distinct polymorphic forms (space groups P1̄ and P21212), arising from differences in the network of no... ...