Nicotinoyl hydrazone-directed vanadium assemblies: metallosupramolecular isomerism, polymorphism, and catalytic oxidation performance [0.03%]
尼古特 Hydrazone-导向的钒组件：金属超分子异构体，多形性以及催化氧化性能
Edi Topić,Josipa Sarjanović,Dino Kuzman et al.
Edi Topić et al.
A systematic investigation of coordination-driven vanadium assemblies reveals a rich structural landscape in which tetrameric metallacycles [VO(VanNH)(OR)]4 and 1D polymeric species [VO(VanNH)(OR)]n form selectively, depending on reaction c...
Theoretical study of ether group substitution effects on the electrochemical properties of Ti-modified vanadium-oxide clusters [0.03%]
理论研究醚基团取代对Ti修饰钒氧化物纳米簇电化学性能的影响
Kexin Wang,Shuang Wu,Sihan Wei et al.
Kexin Wang et al.
In this study, the effects of ether group substitution on the electrochemical properties of [Ti2V4O5(OCH3)14] (Ti2V4) and [Ti3V3O4(OCH3)15]+ (Ti3V3+) were investigated by combining density functional theory (DFT) calculations and molecular ...
A dual-phase luminescent phosgene sensor based on an AIE-active ruthenium(II) polypyridine complex [0.03%]
一种基于聚集诱导发光钌(ii)多吡啶配合物的双模光气传感器
Sumit Kumar Patra,Jogat Gogoi,Monosh Rabha et al.
Sumit Kumar Patra et al.
Herein, we report a bis-heteroleptic ruthenium(II) complex 1[PF6]2 carrying two o-phenylenediamine groups (OPD) connected to the 4,7-positions of a 1,10-phenanthroline ligand. Compound 1[PF6]2 shows aggregation-induced emission enhancement ...
Design and synthesis of Zn(II)/Cd(II)-based energetic metal coordination polymers with the bis(tetrazole)methane (H2btm) ligand: a comparative assessment of heat resistance and catalytic effects on the thermal decomposition of ammonium perchlorate [0.03%]
基于Zn(II)/Cd(II)的含能金属配位聚合物(H_2btm配体)的设计、合成及热稳定性与催化性能研究
Priyanka Singla,Vanshika Sharma,Yashita et al.
Priyanka Singla et al.
We report two energetic metal coordination polymers (CPs), [Zn(Hbtm)2]n (1) and [Cd3(btm)2Br2(H2O)2]n·4H2O (2), based on the bis(tetrazole)methane (H2btm) ligand. SCXRD analysis shows that 1 forms a 2D layered structure extending into a 3D...
Ni(II)-oxalate on plastic-derived carbon: a green platform for furfural diacetal synthesis [0.03%]
塑料衍生碳基绿色平台高效合成糠醛二缩醛
Alexander Pokutsa,Salvador Perez-Huertas,Alina Mariana Balu et al.
Alexander Pokutsa et al.
An efficient and environmentally benign method for the synthesis of diacetals from furfural (FF) and heavy aliphatic (1-hexanol) or alicyclic (cyclohexanol) alcohols is reported for the first time. A novel catalyst comprising 2.5 wt% Ni(II)...
E Dalles Keyes,Sophia E Hollow,Paul Oblad et al.
E Dalles Keyes et al.
The human protein histidine phosphatase PHPT1 is involved in several important cellular pathways and has been implicated in various cancers. However, the biological roles of this enzyme are not well understood due to a lack of chemical tool...
Half-sandwich η5-pyrrolyl rhodium(I) complexes with alkene coordination: synthesis and reactivity exploration [0.03%]
半夹心η5-吡咯基铑(I)与烯烃配位配合物的合成及反应性研究
Jiayu Yan,Jian Sun,Shuangliu Zhou
Jiayu Yan
Rhodium alkene complexes with η5-pyrrolyl ligands are successfully synthesized and fully characterized by X-ray analyses and NMR spectroscopy. The dynamics of pyrrolyl and alkene coordination as well as the combined σ- and π-ligation abi...
Ligand decorated nickel-based nanoparticles supported onto MXenes in catalytic hydrogenation of N-heterocycles [0.03%]
配体修饰的镍基纳米颗粒负载于MXene上用于N-杂环化合物催化氢化反应中
Judith Medina-Vargas,Santiago Martín,Iván Sorribes et al.
Judith Medina-Vargas et al.
The development of efficient first-row transition metal catalysts is essential for advancing sustainable chemical processes. In this study, we report the synthesis of nickel-based nanoparticles (NiNPs) functionalized with N-heterocyclic car...
Crystal structures and optical properties of two layered lead halide phosphites Pb3(HPO3)Cl4·H2O and Pb3(HPO3)2Cl2·H2O [0.03%]
两种含铅卤化物磷酸盐的晶体结构和光学性质：Pb3(HPO3)Cl4·H2O和Pb3(HPO3)2Cl2·H2O
Zong-Jie Zhao,Yu-Zheng Yan,Jia-Jian Fu et al.
Zong-Jie Zhao et al.
Two new all-inorganic lead halide phosphites, Pb3(HPO3)Cl4·H2O and Pb3(HPO3)2Cl2·H2O, have been synthesized and structurally characterized as layered frameworks constructed from distorted Pb-O(H2O) polyhedra linked by pseudo-tetrahedral H...
Tetrazine-functionalized UiO-68 for highly selective Au(III) recovery from acidic solutions [0.03%]
用于酸性溶液中Au(III)高选择性回收的四嗪功能化UiO-68
Zhuoran Sun,Yali Ma,Haijun Hu et al.
Zhuoran Sun et al.
A tetrazine-functionalized zirconium MOF, UiO-68-TZDC (isostructural with UiO-68-TPDC), is constructed through a one-pot solvothermal synthesis for the selective recovery of Au(III) from acidic chloride media, using UiO-68-TPDC as a tetrazi...