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Design and synthesis of Zn(II)/Cd(II)-based energetic metal coordination polymers with the bis(tetrazole)methane (H2btm) ligand: a comparative assessment of heat resistance and catalytic effects on the thermal decomposition of ammonium perchlorate

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We report two energetic metal coordination polymers (CPs), [Zn(Hbtm)2]n (1) and [Cd3(btm)2Br2(H2O)2]n·4H2O (2), based on the bis(tetrazole)methane (H2btm) ligand. SCXRD analysis shows that 1 forms a 2D layered structure extending into a 3D supramolecular netw... ...