Crystal growth of metal tellurides from a boron-tellurium mixture: MTr2Te4 (M = Sr, Eu; Tr = In, Ga) [0.03%]
由硼-碲混合物生长金属碲化物的晶体：MTr₂Te₄（M=Sr，Eu；Tr=In，Ga）
Subhendu Jana,E A Chirantha Edirisinghe,Machima Mongkhonratanachai et al.
Subhendu Jana et al.
A boron-tellurium mixture was employed as a reactive molten salt to prepare single crystals and polycrystalline powders of three ternary tellurides, MTr2Te4 (M = Sr, Eu; Tr = In, Ga), starting from binary metal oxides. This method represent...
Surface interaction, polarity and probe mobility differences on organophosphonic-acid modified titania: a spin probe EPR study [0.03%]
有机磷酸钛酸盐修饰二氧化钛表面的自旋标记EPR研究：来自表面相互作用、极性和探针扩散性的证据
Rui An,H Y Vincent Ching,Lisa Van der Heyden et al.
Rui An et al.
Many applications of organophosphonic-acid-grafted titania materials rely directly on their surface properties. Despite a manifold of studies on this type of material, limited information is currently available on the differences in (local)...
Pendant-cation assisted spontaneous axial halide substitution in group 7 M(L)(CO)3X complexes [0.03%]
第七族M(L)(CO)₃X配合物中 pendant-阳离子辅助的轴向卤素自发取代反应
Wesley W Kramer,Thomas R Sheridan,Jorge Pérez-Vázquez et al.
Wesley W Kramer et al.
The installation of cationic pendant groups proximal to catalyst active sites has resulted in improved performance for electrocatalytic CO2 reduction (CO2R) by molecular catalysts. It is not well understood how pendant cationic groups, desi...
A di-nuclear μ-oxido rhenium(VI) complex: from deep purple to catalytic applications [0.03%]
一个含μ-过氧桥的二核铼（VI）配合物：从深紫色到催化应用
Tobias A Doliner,Peter E Hartmann,Gernot Oberwinkler et al.
Tobias A Doliner et al.
In this manuscript, we report on the formation and isolation of the di-nuclear rhenium(VI) µ-oxido bridged complex {[ReOCl2(L1)]}2(µ-O) (1), which we nick-named "deep purple" due to its intense purple color both in the solid state as well...
Preparation of graphdiyne for efficient capacitive extraction of U(VI) from water samples [0.03%]
用于水样中高效电容提取U(VI)的图亚烯的制备
Xuena Chen,Yuang Liu,Zitong Song et al.
Xuena Chen et al.
In this work, a one-step hydrothermal condensation process was used to prepare graphdiyne (GDY), which was then used as an electrode material for the capacitive extraction of U(VI) from wastewater. The synthesized GDY exhibited a multilayer...
Efficient synthesis of cyclic carbonates and oxazolidinones by simple zinc guanidinato complexes [0.03%]
简单的锌呱啶
Carlos Ginés,Blanca Parra-Cadenas,David Elorriaga et al.
Carlos Ginés et al.
Guanidinato-stabilized zinc complexes, featuring or lacking additional functionalities, were synthesized through the reaction between guanidine derivatives, specifically (iPrHN)2CNR (R = Ph, 2-FC6H4, 2-Ph2PC6H4, 2-PhSC6H4), and ZnMe2. The s...
Growth and luminescence properties of pure, Ce-doped and Eu-doped LiSr2I5 single crystals [0.03%]
纯的和Ce、Eu掺杂的LiSr₂I₅单晶的生长及发光性质研究
Ting Feng,Xinhui Jia,Xi Chong et al.
Ting Feng et al.
In this work, pure, Ce3+-doped, and Eu2+-doped LiSr2I5 single crystals were grown, and the effects of ion doping on their luminescence properties were investigated. Single crystals with diameters of 10 and 15 mm were grown using the vertica...
Magneto-structural and theoretical insights into Ni2Dy2 butterfly single-molecule magnets with diverse anionic co-ligands [0.03%]
具有多种阴离子共配体的Ni2Dy2蝶状单分子磁体的磁结构及理论研究视角
Anangamohan Panja,Zvonko Jagličić,Daniel Aravena et al.
Anangamohan Panja et al.
Five defective dicubane Ni2Dy2 complexes with the general formula [Ni2Dy2(L)4X2(solvent)n], where (X = NO3- (1), acetylacetonate (2), NCS- (3), OAc- (4), and pivalate (5)), were synthesized and structurally characterized to investigate how ...
Fabrication of a hollow-shaped CuO nanoparticle assembly using a sacrificial W18O49 template for C2+-product-selective electrochemical CO2 reduction [0.03%]
利用W18O49模板构建中空CuO纳米粒子组装体用于C2+产物选择性电催化CO2还原反应
Shan Wang,Chen Yang,Feng Chen et al.
Shan Wang et al.
Tungsten suboxide (W18O49) was used as a sacrificial template to prepare a hollow-shaped assembly of CuO nanoparticles as an active and stable catalyst for electrochemical CO2 reduction. Catalyst precursor materials Cu-W18O49-x (x denotes t...
Expanding the reactivity of Rosenthal's reagent to cyclopropenes and allenes [0.03%]
罗森塔尔试剂反应性的扩大使其能够与环丙烯和全烯发生反应
Marcel Eilers,Dennis Geik,Marc Schmidtmann et al.
Marcel Eilers et al.
The reactions of the Rosenthal reagent Cp2Ti(η2-BTMSA) with cyclopropenes and allenes were systematically investigated. With cyclopropenes, selective 1,2-insertion into the Ti-C bond induces a ring expansion from three- to five-membered fr...