Efficient synthesis of cyclic carbonates and oxazolidinones by simple zinc guanidinato complexes
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Guanidinato-stabilized zinc complexes, featuring or lacking additional functionalities, were synthesized through the reaction between guanidine derivatives, specifically (iPrHN)2CNR (R = Ph, 2-FC6H4, 2-Ph2PC6H4, 2-PhSC6H4), and ZnMe2. The simple complex [ZnMe{... ...