Zeolite synthesis from coal gangue: a response surface methodology approach for optimal conditions [0.03%]
煤矸石合成分子筛：采用响应面法探究最优工艺条件
Yilin Chen,Yanshuang Chen,Hanqi Xu et al.
Yilin Chen et al.
The formation process of zeolites is influenced by multiple factors, and the traditional single-variable approach lacks sufficient explanatory power in elucidating the principles governing crystal synthesis. In this study, the response surf...
Synthesis and anticancer activity of cyclometalated Pt(II) neutral complexes containing curcumin as a bioactive ancillary ligand [0.03%]
含姜黄素生物配体的Pt（II）中性环金属配合物的合成及其抗肿瘤活性研究
Eugenia Giorno,Giorgio Facchetti,Nicolas Godbert et al.
Eugenia Giorno et al.
A novel series of cyclometalated platinum(II) complexes of curcumin, [(C^N)Pt(curc)] 1-5, was synthesized via a microwave-assisted procedure, using NEt3 as the base, which offers a safer and more efficient alternative to traditional synthet...
Isostructural Mg and Zn compounds: analogies and differences in reactivity [0.03%]
同结构的镁和锌化合物：反应活性的相似性和差异性
Kriti Pathak,Suban Kundu,Sheetal Kathayat Bisht et al.
Kriti Pathak et al.
In recent years, active efforts to assess similarities and differences in the reactivity of isostructural magnesium and zinc complexes have witnessed reasonable growth. The advancements in their chemistry concerning catalytic reduction of c...
Intramolecular sensitization and structure of a Tb3+/2-hydroxyquinoline conjugate in the paraoxonase 1 active site [0.03%]
铽(III)/2-羟基喹啉共轭物在弹力蛋白酶I活性位点内的分子内敏化及结构研究
Janez Smerkolj,Miha Bahun,Nataša Poklar Ulrih et al.
Janez Smerkolj et al.
Paraoxonase 1 (PON1) is a Ca2+-dependent enzyme involved in oxidative stress processes and is widely studied for its protective roles in various diseases. Intermolecular sensitization of lanthanide ions was implemented by replacing Ca2+ ion...
Dinuclear aluminum complex as an active material for RRAM switching devices [0.03%]
双核铝配合物作为RRAM开关器件的活性材料
Vivek Sharma,Anupam Chetia,Moumita Majumder et al.
Vivek Sharma et al.
In this study, we report the synthesis and structural characterization of dinuclear aluminum complex 1, containing redox-active bis-catecholaldimine ligand 6,6'-{[ethane-1,2-diylbis(azanylidene)]bis(methanylidene)}-bis(3,5-di-tert-butyl-1,2...
Stepwise azido transfer to cerous tris(tert-butoxy)siloxide via trans-silylation with Me3SiN3 [0.03%]
硝酸铈胺与Me3SiN3的逐级硅转移反应生成叠氮𬭩盐的研究
Jochen Friedrich,Jonas Riedmaier,Cäcilia Maichle-Mössmer et al.
Jochen Friedrich et al.
Trimethylsilylhalogenides and -pseudohalogenides are frequently used reactants for (pseudo)halogen transfer, including derivatizations of cerium compounds. The present study describes the facile ligand exchange of cerium(III) complex [Ce{OS...
Unlocking the Potential of MoS2@ZnFeS Nanosheet Catalyst as an Anode Electrode Material for Synergistic Improvement of Capacity and Durability in Lithium-Ion Battery Performance [0.03%]
MoS2@ZnFeS纳米片催化剂作为锂离子电池负极电极材料的潜力及其对容量和耐久性协同提升的影响研究
Mallappa Mahanthappa,Shahbaz Ahmed,Debabrata Chanda et al.
Mallappa Mahanthappa et al.
It is indispensable to enhance the capacity and stability of electrodes to improve the overall activity of lithium-ion batteries. This study explores the development of a lithium-ion battery (LIB) anode using a molybdenum disulfide and zinc...
Porphyrin-functionalized glassy carbon electrodes for electrochemical water splitting [0.03%]
用于电化学水分解的卟啉功能化石墨玻碳电极
Neidy Ocuane,Nasim Jafari,Jonathan J Calvillo Solis et al.
Neidy Ocuane et al.
Herein, we electrografted the free-base 5,10,15,20-tetrakis(4-aminophenyl)porphyrin, (H2TAPP) and the cobalt-based porphyrin (CoTAPP) onto the surface of glassy carbon electrodes (GCE) which results in a H2TPP-GCE and CoTPP-GCE polymer, res...
Hydrogen bonds in the second coordination sphere of metal complexes in the gas phase - playing by the rules? [0.03%]
气相中金属配合物第二配位壳层中的氢键——受规则约束吗？
Dušan P Malenov,Jelena M Živković,Snežana D Zarić
Dušan P Malenov
Hydrogen bonds in the second coordination sphere of metal complexes play a crucial role in the fine-tuning of their chemical and physical properties, including catalytic activity and selectivity. Our gas-phase computational study on hydroge...
A detailed study on the effects of adsorbed water molecules on proton conduction in a metal-organic framework [0.03%]
吸附水分子对金属有机框架中质子传导影响的详细研究
Kyoko Shiraishi,Mitsuki Kabaya,Kouki Fujihira et al.
Kyoko Shiraishi et al.
We demonstrate the proton-conductive properties of Zr-BPT, having one-dimensional pores. The MOF shows superprotonic conductivity of 3.6 × 10-4 S cm-1 at room temperature (25 °C). The conduction mechanism was discussed with the relationsh...