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Stepwise azido transfer to cerous tris(tert-butoxy)siloxide via trans-silylation with Me3SiN3

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Trimethylsilylhalogenides and -pseudohalogenides are frequently used reactants for (pseudo)halogen transfer, including derivatizations of cerium compounds. The present study describes the facile ligand exchange of cerium(III) complex [Ce{OSi(OtBu)3}3]2 with Me... ...