Rational structural design of aromatic Azo photoactive small molecules for biomedical applications [0.03%]
用于生物医学应用的芳香重氮光活性小分子的理性结构设计
Junjie Ding,Ze Huang,Duoteng Zhang et al.
Junjie Ding et al.
Aromatic Azo molecules, including azobenzenes (Ph-NN-Ph) and heteroaryl Azo (Het-NN-Ph or Het-NN-Het), have emerged as versatile and high-performing photoactive switches for biomedical applications. Despite decades of extensive resear...
Recent advances in the transformation of nitriles into diverse N-heterocycles [0.03%]
近期通过转化腈类制备多种氮杂环的研究进展
Wenting Huang,Dandan He,Huanfeng Jiang et al.
Wenting Huang et al.
Nitriles, as valuable compounds characterized by carbon-nitrogen triple bonds, represent an important class of synthons in organic synthetic chemistry and materials science. Over the past two decades, the conversion of nitriles to diverse N...
Kan Yao,Gaoyang Kong,Chengyu Xiao et al.
Kan Yao et al.
Maintenance of temperature within a suitable range is essential for human activity, and thermal management is the science dedicated to this goal. From an optical point of view, thermal management requires engineered photonic materials with ...
Prakash Kafle,Deacon Herndon,Indrajeet Sharma
Prakash Kafle
Sulfenylcarbenes and sulfenylnitrenes are ambiphilic intermediates possessing an unoxidized sulfur atom adjacent to their reactive center. Their unique properties and tunable reactivity make them a model species for studying carbenes and ni...
Au NHC complexes as anticancer agents: milestones, strategies and future developments [0.03%]
含金氮杂环卡宾复合物作为抗肿瘤药物的研究：里程碑、策略及未来发展方向
Melanie E Hoffmann,Fritz E Kühn
Melanie E Hoffmann
The need for selective and efficient anticancer therapies drives the development of gold N-heterocyclic carbene (NHC) as efficient metallodrugs. Their stability, tunable electronics, and versatile steric features make NHCs ideal ligands, wh...
Radical retrosynthesis: a powerful strategy for modern assembly of terpenoid natural products [0.03%]
激进的逆合成分析：现代萜类天然产物合成的强大策略
Yong Zhang,Yanbo Zhang,Chao Li
Yong Zhang
Radical retrosynthesis has emerged as a powerful strategy for the modern assembly of complex natural products, offering a one-electron logic that complements traditional polar disconnections. This review highlights recent advances-particula...
Yanan Li,Wen Zhao,Yonghua Wu et al.
Yanan Li et al.
In vivo biosensing is essential for real-time monitoring of biological processes and disease progression within living organisms. Leveraging the programmable specificity and multifunctionality of CRISPR effectors, in vivo CRISPR-based biose...
Scanning probe microscopy of metal-organic coordination systems: characterization of monolayers, single crystals, discrete architectures [0.03%]
金属有机配位系统的扫描探针显微镜研究：单分子层、单晶和离散结构的表征
Antonino Cucinotta,Jack A Davies,Kunal S Mali et al.
Antonino Cucinotta et al.
Metal-organic coordination is omnipresent in a number of functional materials. Such systems are highly diverse in terms of their composition, complexity, and dimensionality. They include two-dimensional (2D) and three-dimensional (3D) struc...
Spin-engineered catalysts: unlocking new frontiers in environmental and energy catalysis applications [0.03%]
自旋工程催化剂：环境与能源催化应用新前沿
Bofan Zhang,Zhengyang Tong,Junhu Wang et al.
Bofan Zhang et al.
Environmental catalysis is pivotal in addressing pollution and advancing energy conversion technologies. Spin, an intrinsic particle property of a material, significantly influences catalytic reactions by altering the electronic structure o...
Yuxin Shi,Seong Eui Chang,Tae-Woo Lee
Yuxin Shi
Perovskite light-emitting diodes (PeLEDs) that use lead (Pb)-based perovskites are promising candidates for the next generation of lighting and display technologies. However, concerns about the toxicity of Pb have delayed their progress tow...