A unified quantum rate theory of electron transfer: conceptual advances in quantum electrochemistry [0.03%]
统一的量子速率理论在电子转移中的应用：量子电化学的概念进展
Paulo Roberto Bueno
Paulo Roberto Bueno
This viewpoint on recent advances in quantum electrochemistry demonstrates how quantum-rate (QR) theory unifies the Levich, Dogonadze, and Kuznetsov (LDK) and Marcus electron-transfer (ET) theories from the 1960s within a common framework. ...
Precise synthesis of conjugated polymers via reducing homocoupling defects [0.03%]
通过减少同偶联缺陷精确合成共轭聚合物
Bowei Ma,Qinqin Shi,Hui Huang
Bowei Ma
In recent years, π-conjugated polymers (CPs) have garnered significant attention for their versatile applications in optoelectronics, energy storage, and sensing technologies. This heightened interest stems from their advantageous properti...
Wei Xu,Yu-An Li,Pufeihong Xia et al.
Wei Xu et al.
Nano-impact electrochemistry (NIE) probes electrochemical function one nanoparticle at a time. Freely diffusing particles stochastically collide with an ultramicroelectrode, and each impact produces a current transient that reports single-e...
Cyclopropane-to-organoboron conversion via C-H and C-C bond activation [0.03%]
通过C-H和C-C键活化将环丙烷转化为有机硼化合物
Shuyu Kang,Xueli Lv,Zhuangzhi Shi
Shuyu Kang
Organoborons have emerged as a class of privileged building blocks in modern organic synthesis, enabling unparalleled molecular diversity and serving as versatile carboxylic acid bioisosteres with profound implications in drug discovery. Co...
Multifaceted maleimide scaffolds in focus: from synthesis to photophysical applications [0.03%]
马来酰亚胺多功能支架：从合成到光物理应用
Marcelo H R Carvalho,Gabriel M F Batista,Pedro P de Castro et al.
Marcelo H R Carvalho et al.
Substituted maleimides, particularly those bearing substitution at the 3- or 3,4-positions, are valuable building blocks in organic synthesis and chemical biology. While classical methods for their preparation rely on halogenated precursors...
Shiqi Hu,Cherry Park,Sebin Jeong et al.
Shiqi Hu et al.
The emergence of additive manufacturing techniques offers more opportunities for fabricating complex structures with designed properties that are challenging to achieve using traditional manufacturing methods. Micro-/nano-scale metastructur...
Transient absorption spectroscopy: a mechanistic tool for triplet sensitizers and their applications [0.03%]
瞬态吸收光谱：三重态光敏剂的作用机制及其应用的工具
Mushraf Hussain,Samana Batool,Zafar Mahmood et al.
Mushraf Hussain et al.
Transient absorption spectroscopy (TAS) is a well-known technique used to study events that take place upon photoexcitation at short time scales (usually from femtoseconds to nanoseconds and up to milli-seconds) and involve processes such a...
Nucleic acid nanotechnology in tumor microenvironment research: from illumination to intervention for enhanced immunotherapy [0.03%]
核酸纳米技术在肿瘤微环境研究中的应用：从阐明到干预，以增强免疫疗法
Jiayi Lu,Wei Zhai,Min Li et al.
Jiayi Lu et al.
Nucleic acid nanotechnology has emerged as a transformative tool in tumor research due to several unique properties including exceptional programmability and biocompatibility. The simplicity of their synthesis and chemical modification, the...
Clarissa Lim,Deborah Seah,Marc Vendrell
Clarissa Lim
Fluorescence lifetime imaging has emerged as a promising modality to extract molecular information from biological systems, providing detailed and semi-quantitative characterisation of subcellular microenvironments. Fluorescence lifetime me...
Metal-organic framework-based gas sensors: fabrication, mechanisms, and applications [0.03%]
金属有机骨架基气体传感器：制备、机理及应用
Jianzhong Zheng,Yuxuan Xie,Wen-Hua Li et al.
Jianzhong Zheng et al.
Gas-sensing technologies facilitate the early detection and prediction of unforeseen future events by tracking surrounding invisible and instantaneous molecular information, which is critical for applications in agriculture, medicine, chemi...