Revealing cobalt-induced Li-ion trapping at the LATP/LCO interface with a fine-tuned machine learning interatomic potential [0.03%]
具有精调机器学习间原子势的LATP/LCO界面的钴诱导Li离子捕获现象的研究
Yu-Ting Tai,Hong-Kang Tian
Yu-Ting Tai
We investigate how Co migration from LiCoO2 into the solid electrolyte LATP impacts Li-ion transport using fine-tuned machine learning interatomic potentials. Our simulations reveal that Co substitution at Ti sites induces local Li-ion trap...
Chang-Hui Liu,Su-Yang Xu,Xue-Ting Li et al.
Chang-Hui Liu et al.
Organic halides are vital in the synthesis of pharmaceuticals, agrochemicals, and materials. While conventional alkene dihalogenation uses active halogen reagents, we developed an electrochemical strategy for selective bromochlorination. Th...
Unveiling the unusual halochromic response and phase behavior of a dihydropyrrolo[3,2- b]pyrrole electrochrome [0.03%]
一种二氢吡咯并吡咯类电致变色材料的非常规溶剂化响应及相行为研究
Vanessa Phan,Perry Skiouris,Jonathan Lawton et al.
Vanessa Phan et al.
A carbazole-functionalized pyrrolo[3,2-b]pyrrole (Cbz-DHPP) chromophore was synthesized, exhibiting high-contrast electrochromism, strong blue fluorescence, halochromism, and polymorphism. These findings advance understanding of DHPP struct...
Charge-transfer modulated chiroptical azacyclooctatetraene-fused [5]helicenes with AIE features [0.03%]
具有AIE特性的电荷转移调控手性螺环类化合物
Xiaojun Yin,Xuefeng Chen,Xuechao Mo et al.
Xiaojun Yin et al.
Azacyclooctatetraene-fused [5]helicene scaffolds are integrated with phenazine to afford broadly tunable thermally activated delayed fluorescence emitters (peaks ranging from 555 to 843 nm). The new emitters exhibit circularly polarized lum...
In situ electrostatic assembly of ZnO nanocrystals and 2D graphene-like porous SOFs for synergistic boosting of electrochemiluminescence performances [0.03%]
基于ZnO纳米粒子和二维石墨烯类似物的类分子有机框架材料的原位静电组装及电致化学发光性能增强研究
Ke-Hui Wei,Qian Liu,Ming-Xuan Jia et al.
Ke-Hui Wei et al.
ZnO nanocrystals and 2D graphene-like porous supramolecular organic framework (SOF) nanocomposites were fabricated by following an in situ electrostatic assembly strategy, which yielded a synergistic enhancement of electrochemiluminescence ...
Quantitative framework for the definition of planar spatial resolution in scanning electrochemical microscopy [0.03%]
扫描电化学显微镜中平面空间分辨率的定量界定框架
Geonwoo Park,Haesung Oh,Yeonsu Kim et al.
Geonwoo Park et al.
This study presents a set of quantitative criteria for the definition of planar spatial resolution in scanning electrochemical microscopy (SECM) imaging using an effective diffusion ellipsoid (EDE) model. Experiments and simulations confirm...
Accessing [6,6,5,6] tetracyclic indeno-quinolines via a photomediated cascade reaction of electron-rich 1,7-enynes [0.03%]
通过电子丰富的1,7-炔烃的光介导级联反应获得[6,6,5,6]四环茚并喹啉类化合物
Pooja Yadav,A Anagha Varma,Purushothaman Gopinath
Pooja Yadav
Synthesis of various sulfonyl- and trifluoromethyl-decorated tetracyclic indeno-quinolines from 1,7-enynes via a cascade radical addition-cyclization-aromatization sequence is presented. The reaction was found to show broad substrate scope ...
meta-NTf2 substituted diaryliodonium salts: novel nitrogen-substituted aryne precursors for trapping reactions and rearrangements [0.03%]
氮取代的茋重氮盐：用于捕捉反应和重排的新 Aryne 前体
Junjie Jiang,Lifeng Chu,Limin Wang et al.
Junjie Jiang et al.
We synthesized meta-NTf2-substituted diaryliodonium salts as novel aryne precursors, the resulting aryne intermediates underwent efficient trapping reactions with various arynophiles, enabling the difunctionalization of the benzene ring. Fu...
Anilkumar Kommoju,Saraswathy Ramalingam,Saikumar Boddepalli et al.
Anilkumar Kommoju et al.
In recent times, iron-based dual/photoredox catalysis has evolved as a green and sustainable approach, enabling various complex organic transformations with a broad substrate scope and good selectivity. It is a cost-effective and efficient ...
Hydrogen-bonded organic frameworks leveraging Lewis basic motifs for high-capacity iodine capture [0.03%]
利用路易斯碱基序构建的氢键有机框架用于高容量捕获碘原子
Ming-Zhi Zhuo,Xin-Yu Yan,Zi-Hang Yang et al.
Ming-Zhi Zhuo et al.
Hydrogen-bonded organic frameworks (HOFs) possess great potential for addressing the threat of radioactive iodine. Here, we report a π-electron-enriched HOF incorporating pyridine nodes as an efficient and recyclable iodine capture platfor...