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Plasmonic TiN-supported CuPd alloy for highly selective and base-free photocatalytic Glaser homocoupling

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An ice-templated CuPd/TiN catalyst is reported for efficient, base-free photocatalytic Glaser homocoupling. Synergizing TiN's LSPR effect with CuPd alloying, the system achieves 99% conversion and 100% selectivity. XAS-confirmed electron transfer from Cu to P... ...