Design and synthesis of advanced electrode materials: from Li-ion to Na-ion batteries [0.03%]
先进电极材料的设计与合成：从锂离子电池到钠离子电池
Hyojun Lim,Jaekyung Sung,Ji-Won Jung et al.
Hyojun Lim et al.
The rising demand for lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) as power sources has increased the need for advanced electrode materials that offer improved electrochemical performance and structural durability. While res...
Nitrogen atom insertion into NN double bonds: straightforward access to triazenes [0.03%]
氮原子插入NN双键：合成三氮烯的直接方法
Prashant Kumar,Ruchir Kant,Namrata Rastogi
Prashant Kumar
The present work documents the insertion of one nitrogen atom into a diazene moiety, providing direct access to the triazene core. N-Amino pyridinium iodide was used as the single-nitrogen-atom transfer reagent in the reaction. The strategy...
Visible-light-driven cascade cyclization: a modular approach to functionalized 4-pyrrolin-2-ones [0.03%]
可见光促进级联环化反应构建功能化的四氢吡咯酮类化合物
Rupashri Dash,Karan Ramdas Thombare,Anindya Das et al.
Rupashri Dash et al.
We report an efficient and modular strategy for the construction of densely functionalized 4-pyrrolin-2-ones via visible-light-driven Ru(II) photocatalysis. The radical cascade cyclization approach enables the diversity-oriented synthesis o...
Information-rich sensors by assembly: a review on the use of macrocyclic hosts in the context of complex chemical systems [0.03%]
基于大环主体的富信息传感器组装：复杂化学体系中的应用综述
Allison J Selinger,Fraser Hof
Allison J Selinger
Host-based sensors that offer cross-reactivity to analytes can be valuable tools in the detection and differentiation of biologically relevant molecules. This review Feature Article provides a foundational background in developing macrocycl...
Advanced mechanical polymer nanocomposites: from confined interphase to structural synergy [0.03%]
高级机械聚合物纳米复合材料：从受限界面到结构协同作用
Hangsheng Zhou,Hao Zha,Zongzheng Zhang et al.
Hangsheng Zhou et al.
Lightweight and high-performance polymer nanocomposites are essential for diverse applications in structural materials, energy storage, and biomedical devices. Inspired by natural biomaterials with excellent mechanical and functional proper...
Glass-like thermal transport in polycrystalline perovskite lithium-ion conductor Li3/8Sr7/16Hf1/4Ta3/4O3 [0.03%]
多晶钙钛矿型锂离子导体Li3/8Sr7/16Hf1/4Ta3/4O3中的玻璃态热输运现象
Yitian Wang,Qianru Jia,Shuchen Li et al.
Yitian Wang et al.
Understanding the thermal properties of lithium-ion conductors is vital for optimizing heat dissipation and enhancing the overall performance, reliability, and safety of all-solid-state batteries. Here, we investigate the specific heat and ...
An endoplasmic reticulum-targeted NIR-II type I AIE photosensitiser for triggering pyroptosis [0.03%]
一种靶向内质网的近红外二区I型AIE光敏剂用于诱导细胞炎性焦亡死亡
Xinyu Li,Lijin Yang,Bingbing He et al.
Xinyu Li et al.
In this work, we developed an endoplasmic reticulum-targeted NIR-II photosensitizer (TI-ER), which exhibits type I ROS generation and photothermal capabilities. After formulation into nanoparticles (NPs), TI-ER NPs were efficiently internal...
AI-driven advances in metal-organic frameworks: from data to design and applications [0.03%]
基于人工智能的金属有机框架研究进展：从数据到设计及应用
Yuhang Song,Jiakai Li,Dongzhi Chi et al.
Yuhang Song et al.
Metal-organic frameworks (MOFs) are a versatile class of porous materials with unprecedented structural tunability, surface area, and application potential in areas such as gas storage, carbon capture, and biomedicine. However, their immens...
Recent developments in high-pressure promoted cycloaddition reactions: experimental and theoretical perspectives [0.03%]
近年来高压促进环加成反应的研究进展：实验与理论视角
Nathan Noël,Rayhane Hammami,Laëtitia Chausset-Boissarie et al.
Nathan Noël et al.
Cycloadditions are fundamental transformations in the synthetic chemist's toolkit, though they can sometimes lead to disappointing results due to steric or electronic constraints. High-pressure conditions offer an effective alternative stra...
In operando assessment of H2O2 production by a multicopper oxidase under direct electron transfer with a gold electrode [0.03%]
金电极直接电子转移条件下多铜氧化酶原位生成H2O2的研究
Panpan Wang,Vânia Brissos,Lígia O Martins et al.
Panpan Wang et al.
A deeper understanding of the intricate redox processes at biotic/abiotic interfaces requires advanced analytical tools. We present the localized and real-time characterization of a multicopper oxidase adsorbed on a gold electrode using a d...